1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole

1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole

In the title compound, C29H24N4O4S3, the two N-tosylbenzimidazolyl unit are connected through a —S—CH2— fragment, the dihedral angle between the benzimidazole rings being 76.09 (5)°. The methylthio group is disordered with respect...

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Main Authors: Nassir N. Al-Mohammed, Yatimah Alias, Zanariah Abdullah, Hamid Khaledi
Format: Article
Language:English
Published: International Union of Crystallography 2011-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811011822
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spelling doaj-6a4830c3d78740179bfbd8ff7bbabc6b2020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675o1043o104310.1107/S16005368110118221-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazoleNassir N. Al-MohammedYatimah AliasZanariah AbdullahHamid KhalediIn the title compound, C29H24N4O4S3, the two N-tosylbenzimidazolyl unit are connected through a —S—CH2— fragment, the dihedral angle between the benzimidazole rings being 76.09 (5)°. The methylthio group is disordered with respect to exchange of the S and C atoms in a 0.547 (4):0.453 (4) ratio. In the crystal, C—H...O and C—H...π interactions connect adjacent molecules into infinite layers parallel to the ab plane. The crystal packing is further stabilized by a π–π interaction [centroid–centroid separation = 3.5187 (4) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536811011822
collection DOAJ
language English
format Article
sources DOAJ
author Nassir N. Al-Mohammed
Yatimah Alias
Zanariah Abdullah
Hamid Khaledi
spellingShingle Nassir N. Al-Mohammed
Yatimah Alias
Zanariah Abdullah
Hamid Khaledi
1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole
Acta Crystallographica Section E
author_facet Nassir N. Al-Mohammed
Yatimah Alias
Zanariah Abdullah
Hamid Khaledi
author_sort Nassir N. Al-Mohammed
title 1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole
title_short 1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole
title_full 1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole
title_fullStr 1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole
title_full_unstemmed 1-Tosyl-2-[(1-tosyl-1H-benzimidazol-2-yl)methylsulfanyl]-1H-benzimidazole
title_sort 1-tosyl-2-[(1-tosyl-1h-benzimidazol-2-yl)methylsulfanyl]-1h-benzimidazole
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-05-01
description In the title compound, C29H24N4O4S3, the two N-tosylbenzimidazolyl unit are connected through a —S—CH2— fragment, the dihedral angle between the benzimidazole rings being 76.09 (5)°. The methylthio group is disordered with respect to exchange of the S and C atoms in a 0.547 (4):0.453 (4) ratio. In the crystal, C—H...O and C—H...π interactions connect adjacent molecules into infinite layers parallel to the ab plane. The crystal packing is further stabilized by a π–π interaction [centroid–centroid separation = 3.5187 (4) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536811011822
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AT yatimahalias 1tosyl21tosyl1hbenzimidazol2ylmethylsulfanyl1hbenzimidazole
AT zanariahabdullah 1tosyl21tosyl1hbenzimidazol2ylmethylsulfanyl1hbenzimidazole
AT hamidkhaledi 1tosyl21tosyl1hbenzimidazol2ylmethylsulfanyl1hbenzimidazole
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