Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)

Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)

The Zn atom in the title compound, [Zn(C7H5O2)2(C12H8N2)(H2O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The axia...

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Main Authors: Peng Gao, Zhan-Wang Shi, Zhong Zhang, Ji-Zhong Liu
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810049639
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spelling doaj-6a242173c52c43f3975762fb5a55d9c82020-11-25T00:50:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m30m3010.1107/S1600536810049639Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)Peng GaoZhan-Wang ShiZhong ZhangJi-Zhong LiuThe Zn atom in the title compound, [Zn(C7H5O2)2(C12H8N2)(H2O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The axial positions are occupied by a carboxylate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N—Zn—O = 146.90 (7)°]. The water molecule forms an intramolecular O—H...O hydrogen bond; an intermolecular O—H...O hydrogen bond gives rise to a dimer. http://scripts.iucr.org/cgi-bin/paper?S1600536810049639
collection DOAJ
language English
format Article
sources DOAJ
author Peng Gao
Zhan-Wang Shi
Zhong Zhang
Ji-Zhong Liu
spellingShingle Peng Gao
Zhan-Wang Shi
Zhong Zhang
Ji-Zhong Liu
Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
Acta Crystallographica Section E
author_facet Peng Gao
Zhan-Wang Shi
Zhong Zhang
Ji-Zhong Liu
author_sort Peng Gao
title Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
title_short Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
title_full Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
title_fullStr Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
title_full_unstemmed Aquabis(benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
title_sort aquabis(benzoato-κo)(1,10-phenanthroline-κ2n,n′)zinc(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description The Zn atom in the title compound, [Zn(C7H5O2)2(C12H8N2)(H2O)], is five-coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The axial positions are occupied by a carboxylate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N—Zn—O = 146.90 (7)°]. The water molecule forms an intramolecular O—H...O hydrogen bond; an intermolecular O—H...O hydrogen bond gives rise to a dimer.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810049639
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AT zhanwangshi aquabisbenzoatoamp954o110phenanthrolineamp9542nnamp8242zincii
AT zhongzhang aquabisbenzoatoamp954o110phenanthrolineamp9542nnamp8242zincii
AT jizhongliu aquabisbenzoatoamp954o110phenanthrolineamp9542nnamp8242zincii
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