catena-Poly[[[aquamanganese(II)]-di-μ-sulfato-[aquamanganese(II)]-μ-N,N,N′,N′-tetrakis(2-pyridylmethyl)hexane-1,6-diamine] hexahydrate]
In the polymeric title compound, {[Mn2(SO4)2(C30H36N6)(H2O)2]·6H2O}n, the two Mn2+ ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)hexane-1,6-diamine (...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807063313 |
| Summary: | In the polymeric title compound, {[Mn2(SO4)2(C30H36N6)(H2O)2]·6H2O}n, the two Mn2+ ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexadentate ligand N,N,N′,N′-tetrakis(2-pyridylmethyl)hexane-1,6-diamine (tphn), forming a one-dimensional chain structure running in the [101] direction. The repeat unit of the polymer, Mn2(SO4)2(H2O)2(tphn), is disposed about a twofold axis passing through the centre of the dinuclear unit. The coordination geometry around the Mn centre is distorted octahedral. Two methylene groups are each disordered equally over two positions. |
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| ISSN: | 1600-5368 |