Materials and Breakdown Phenomena: Heterogeneous Molybdenum Metallic Films

• Main Authors: Augusto Marcelli, Bruno Spataro, Giovanni Castorina, Wei Xu, Stefano Sarti, Francesca Monforte, Giannantonio Cibin
• Format: Article
• Language: English
• Published: MDPI AG 2017-05-01
• Series: Condensed Matter
• Subjects: high gradient structures; breakdown; molybdenum coating; annealed films; transport experiments; X-ray absorption spectroscopy
• Online Access: http://www.mdpi.com/2410-3896/2/2/18

Technological activities to design, manufacture, and test new accelerating devices using different materials and methods is under way all over the world. The main goal of these studies is to increase the accelerating gradients and reduce the probability of radio-frequency (RF) breakdown. Indeed, it is still not clear why, by increasing the intensity of the applied field, intense surface damage is observed in copper structures, limiting the lifetime and, therefore, the practical applications. A possible solution is represented by a coating of a relatively thick layer of molybdenum in order to improve the breakdown rate. molybdenum can be reliably grown on different substrates with a negligible strain and, for thicknesses up to 600 nm, with a resistivity < 100–150·μΩ cm. Moreover, Mo coatings with controlled composition, internal stress, and roughness may allow improving thermo-mechanical properties reaching values not attainable by uncoated copper. Although the Mo conductivity remains lower compared to Cu, a Mo coating represents a very interesting option for high gradient accelerator components manufactured in copper.