Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate

Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate

There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-p...

Full description

Bibliographic Details
Main Authors: Huanyu Liu, Dongsheng Shen
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808039949
id doaj-68d577036cc44446aa0e4f56cf82e20d
record_format Article
spelling doaj-68d577036cc44446aa0e4f56cf82e20d2020-11-24T22:08:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m8m810.1107/S1600536808039949Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvateHuanyu LiuDongsheng ShenThere are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenylphosphino)phenyliminomethyl]ferrocene ligand and two chloride anions.http://scripts.iucr.org/cgi-bin/paper?S1600536808039949
collection DOAJ
language English
format Article
sources DOAJ
author Huanyu Liu
Dongsheng Shen
spellingShingle Huanyu Liu
Dongsheng Shen
Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
Acta Crystallographica Section E
author_facet Huanyu Liu
Dongsheng Shen
author_sort Huanyu Liu
title Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
title_short Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
title_full Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
title_fullStr Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
title_full_unstemmed Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate
title_sort dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2n,p}palladium(ii) dichloromethane hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenylphosphino)phenyliminomethyl]ferrocene ligand and two chloride anions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808039949
work_keys_str_mv AT huanyuliu dichlorido2diphenylphosphinophenyliminomethylferrocene9542nppalladiumiidichloromethanehemisolvate
AT dongshengshen dichlorido2diphenylphosphinophenyliminomethylferrocene9542nppalladiumiidichloromethanehemisolvate
_version_ 1725815367647887360

Similar Items