Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate

Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2N,P}palladium(II) dichloromethane hemisolvate

There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-p...

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Bibliographic Details
Main Authors: Huanyu Liu, Dongsheng Shen
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808039949
Description
Summary:There are two independent PdII complex molecules in the asymmetric unit of the title compound, [PdCl2{Fe(C5H5)(C24H19NP)}]·0.5CH2Cl2. One ferrocenyl ring of one complex molecule is disordered over two sites with half-occupancy for each component. Both PdII cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenylphosphino)phenyliminomethyl]ferrocene ligand and two chloride anions.
ISSN:1600-5368

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