Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques

Fourteen sediment samples were collected along Linggi River, Malaysia. Neutron activation analysis (NAA) and inductively coupled plasma-mass spectrometry (ICP-MS) techniques were used in the determination of toxic element contents. The results showed that As, Cd and Sb concentrations were higher at...

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Main Authors: Md Suhaimi Elias, Shariff Ibrahim, Kamarudin Samuding, Shamsiah Ab Rahman, Yii Mei Wo
Format: Article
Language:English
Published: Elsevier 2018-01-01
Series:MethodsX
Online Access:http://www.sciencedirect.com/science/article/pii/S2215016118300657
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spelling doaj-68d1189629f3425db80c26501b93f6c12020-11-25T01:30:01ZengElsevierMethodsX2215-01612018-01-015454465Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniquesMd Suhaimi Elias0Shariff Ibrahim1Kamarudin Samuding2Shamsiah Ab Rahman3Yii Mei Wo4School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM), 40450, Shah Alam, Selangor, Malaysia; Analytical Chemistry Application Group (ACA), Waste and Environmental Technology Division, Malaysian Nuclear Agency, Bangi, 43000, Kajang, Selangor, Malaysia; Corresponding author at: Analytical Chemistry Application Group (ACA), Waste and Environmental Technology Division, Malaysian Nuclear Agency, Bangi, 43000, Kajang, Selangor, Malaysia.School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM), 40450, Shah Alam, Selangor, MalaysiaEnvironmental Tracer Application Group (E-TAG), Waste and Environmental Technology Division, Malaysian Nuclear Agency, Bangi, 43000, Kajang, Selangor, MalaysiaAnalytical Chemistry Application Group (ACA), Waste and Environmental Technology Division, Malaysian Nuclear Agency, Bangi, 43000, Kajang, Selangor, MalaysiaRadiochemistry and Environmental Group (RAS), Waste and Environmental Technology Division, Malaysian Nuclear Agency, Bangi, 43000, Kajang, Selangor, MalaysiaFourteen sediment samples were collected along Linggi River, Malaysia. Neutron activation analysis (NAA) and inductively coupled plasma-mass spectrometry (ICP-MS) techniques were used in the determination of toxic element contents. The results showed that As, Cd and Sb concentrations were higher at all sampling stations, with enrichment factor values ranging from 17.7 to 75.0, 2.1 to 19.5 and 6.6 to 28.4, respectively. Elements of Pb and Zn) were also enriched at most of the sampling stations whilst Cu, Cr and Ni were shown as background levels. The sediment of Linggi River can be categorised as low (<8.0) to very high degree of contamination (>32.0). The mean concentrations of elements viz. Cd, Cr, Ni, Pb, Sb and Zn were lower than the threshold effect level (TEL) of FSQGs values except for As. The concentration of As (arsenic) was higher than PEL and PEC of FSQGs values. Keywords: Linggi River, Enrichment factor, Degree of contamination, Freshwater sediment quality guidelines, NAA, ICP-MShttp://www.sciencedirect.com/science/article/pii/S2215016118300657
collection DOAJ
language English
format Article
sources DOAJ
author Md Suhaimi Elias
Shariff Ibrahim
Kamarudin Samuding
Shamsiah Ab Rahman
Yii Mei Wo
spellingShingle Md Suhaimi Elias
Shariff Ibrahim
Kamarudin Samuding
Shamsiah Ab Rahman
Yii Mei Wo
Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques
MethodsX
author_facet Md Suhaimi Elias
Shariff Ibrahim
Kamarudin Samuding
Shamsiah Ab Rahman
Yii Mei Wo
author_sort Md Suhaimi Elias
title Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques
title_short Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques
title_full Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques
title_fullStr Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques
title_full_unstemmed Assessment of toxic elements in sediments of Linggi River using NAA and ICP-MS techniques
title_sort assessment of toxic elements in sediments of linggi river using naa and icp-ms techniques
publisher Elsevier
series MethodsX
issn 2215-0161
publishDate 2018-01-01
description Fourteen sediment samples were collected along Linggi River, Malaysia. Neutron activation analysis (NAA) and inductively coupled plasma-mass spectrometry (ICP-MS) techniques were used in the determination of toxic element contents. The results showed that As, Cd and Sb concentrations were higher at all sampling stations, with enrichment factor values ranging from 17.7 to 75.0, 2.1 to 19.5 and 6.6 to 28.4, respectively. Elements of Pb and Zn) were also enriched at most of the sampling stations whilst Cu, Cr and Ni were shown as background levels. The sediment of Linggi River can be categorised as low (<8.0) to very high degree of contamination (>32.0). The mean concentrations of elements viz. Cd, Cr, Ni, Pb, Sb and Zn were lower than the threshold effect level (TEL) of FSQGs values except for As. The concentration of As (arsenic) was higher than PEL and PEC of FSQGs values. Keywords: Linggi River, Enrichment factor, Degree of contamination, Freshwater sediment quality guidelines, NAA, ICP-MS
url http://www.sciencedirect.com/science/article/pii/S2215016118300657
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