Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]

Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]

In the title compound, [Cd(C8F4O4)(C2H5OH)2]n, the CdII cation sits on an inversion centre and is coordinated by six O atoms from four tetrafluorobenzene-1,4-dicarboxylate anions and two ethanol molecules in a distorted octahedral geometry. The anionic ligand is also located on an inversion centre,...

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Main Authors: Nakeun Ko, Jaheon Kim
Format: Article
Language:English
Published: International Union of Crystallography 2013-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813026287
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spelling doaj-68ca42ad2c204686a9666bae7705517e2020-11-25T01:37:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m577m57810.1107/S1600536813026287Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]Nakeun KoJaheon KimIn the title compound, [Cd(C8F4O4)(C2H5OH)2]n, the CdII cation sits on an inversion centre and is coordinated by six O atoms from four tetrafluorobenzene-1,4-dicarboxylate anions and two ethanol molecules in a distorted octahedral geometry. The anionic ligand is also located on an inversion centre, and connects four CdII cations, generating a two-dimensional polymeric layer parallel to the ab plane. Within the layer, the ethanol molecule links F and O atoms of the nearest anionic ligands via O—H...O and O—H...F hydrogen bonds. The ethyl group of the ethanol molecule is disordered over two positions with an occupancy ratio of 0.567 (10):0.433 (10).http://scripts.iucr.org/cgi-bin/paper?S1600536813026287
collection DOAJ
language English
format Article
sources DOAJ
author Nakeun Ko
Jaheon Kim
spellingShingle Nakeun Ko
Jaheon Kim
Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
Acta Crystallographica Section E
author_facet Nakeun Ko
Jaheon Kim
author_sort Nakeun Ko
title Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
title_short Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
title_full Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
title_fullStr Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
title_full_unstemmed Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
title_sort poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-11-01
description In the title compound, [Cd(C8F4O4)(C2H5OH)2]n, the CdII cation sits on an inversion centre and is coordinated by six O atoms from four tetrafluorobenzene-1,4-dicarboxylate anions and two ethanol molecules in a distorted octahedral geometry. The anionic ligand is also located on an inversion centre, and connects four CdII cations, generating a two-dimensional polymeric layer parallel to the ab plane. Within the layer, the ethanol molecule links F and O atoms of the nearest anionic ligands via O—H...O and O—H...F hydrogen bonds. The ethyl group of the ethanol molecule is disordered over two positions with an occupancy ratio of 0.567 (10):0.433 (10).
url http://scripts.iucr.org/cgi-bin/paper?S1600536813026287
work_keys_str_mv AT nakeunko polybisethanol95642356tetrafluorobenzene14dicarboxylatocadmium
AT jaheonkim polybisethanol95642356tetrafluorobenzene14dicarboxylatocadmium
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