Temporal Variation and Chemical Components of Rural Ambient PM_2.5 during Main Agricultural Activity Periods in the Black Soil Region of Northeast China

• Main Authors: Xuewei Wu, Weiwei Chen, Shichun Zhang, Ruimin Li, Mengduo Zhang, Juan Liu, Yibing Jiang, Yang Liu
• Format: Article
• Language: English
• Published: MDPI AG 2019-08-01
• Series: Atmosphere
• Subjects: PM_2.5 concentration; rural; water-soluble ions; trace elements; Northeast China
• Online Access: https://www.mdpi.com/2073-4433/10/9/510

Agricultural emissions are crucial to regional air quality in the autumn and spring due to the intense agricultural activities in Northeast China. However, information on rural ambient particulate matter (PM) in Northeast China is rare, limiting the accurate estimation of agricultural atmospheric particulate matter emissions. In this study, we monitored hourly ambient PM_2.5 (PM with a diameter of less than 2.5 μm) concentrations and analyzed daily chemical components (i.e., water-soluble ions, trace elements, organic carbon, and element carbon) at a rural site in Northeast China during the autumn and spring and assessed the impact of agricultural activities on atmospheric PM_2.5 concentrations. The results showed that the daily average concentrations of PM_2.5 were 143 ± 109 (range: 39−539) μg m^−3 from 19 October to 23 November 2017 (i.e., typical harvesting month) and 241 ± 189 (range: 97−976) μg m^−3 from 1 April to 13 May 2018 (i.e., typical tilling month). In autumn, the ambient PM_2.5 concentrations were high with a Southwest wind, while a Southeast wind caused high PM_2.5 concentrations during spring in the rural site. The concentrations of selected water-soluble ions, trace elements, and carbonaceous fractions accounted for 33%, 4%, and 26% of PM_2.5 mass concentrations, respectively, in autumn and for 10%, 5%, and 3% of PM_2.5 mass concentrations, respectively, in spring. On the basis of the component analysis, straw burning, agricultural machinery, and soil dust driven by wind and tilling were the main contributors to high rural PM_2.5 concentrations. In addition, the increasing coal combustion around the rural site was another important source of PM_2.5.