Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells

Organic&#8722;inorganic halide perovskite solar cells (PSCs) have excellent chemical, electronic, and optical properties, making them attractive next-generation thin-film solar cells. Typical PSCs were fabricated with a perovskite absorber layer between the TiO<sub>2</sub> electron-t...

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Main Authors: MiJoung Kim, MoonHoe Kim, JungSeock Oh, NamHee Kwon, Yoonmook Kang, JungYup Yang
Format: Article
Language:English
Published: MDPI AG 2019-07-01
Series:Sustainability
Subjects:
Online Access:https://www.mdpi.com/2071-1050/11/14/3867
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spelling doaj-67b3294da9eb4df09930c3e7b2a575b72020-11-25T01:26:23ZengMDPI AGSustainability2071-10502019-07-011114386710.3390/su11143867su11143867Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar CellsMiJoung Kim0MoonHoe Kim1JungSeock Oh2NamHee Kwon3Yoonmook Kang4JungYup Yang5Department of Physics, Kunsan National University, Gunsan 54150, KoreaDepartment of Physics, Kunsan National University, Gunsan 54150, KoreaDepartment of Physics, Kunsan National University, Gunsan 54150, KoreaDepartment of Physics, Kunsan National University, Gunsan 54150, KoreaKU-KIST Green School, Graduate School of Energy and Environment, Korea University, Seoul 02841, KoreaDepartment of Physics, Kunsan National University, Gunsan 54150, KoreaOrganic&#8722;inorganic halide perovskite solar cells (PSCs) have excellent chemical, electronic, and optical properties, making them attractive next-generation thin-film solar cells. Typical PSCs were fabricated with a perovskite absorber layer between the TiO<sub>2</sub> electron-transport layer (ETL) and the 2,2&#8242;,7,7&#8242;-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9&#8242;-spirobifluorene (Spiro-OMeTAD) hole-transport layer (HTL). We examined the influence of phenyl-C61-butyric acid methyl ester (PCBM) on the PSC device. PSCs using the PCBM layer as an ETL were investigated, and the absorber layer was coated by dissolving PCBM in a methyl ammonium lead iodide (MAPbI<sub>3</sub>) precursor solution to examine the changes at the perovskite interface and inside the perovskite absorber layer. The PSCs fabricated by adding a small amount of PCBM to the MAPbI<sub>3</sub> solution exhibited a significantly higher maximum efficiency of 16.55% than conventional PSCs (14.34%). Fabricating the PCBM ETL and PCBM-MAPbI<sub>3</sub> hybrid solid is expected to be an efficient route for improving the photovoltaic performance.https://www.mdpi.com/2071-1050/11/14/3867Perovskite photovoltaic devicesphenyl-C61-butyric acid methyl esterMAPbI<sub>3</sub>Efficiency
collection DOAJ
language English
format Article
sources DOAJ
author MiJoung Kim
MoonHoe Kim
JungSeock Oh
NamHee Kwon
Yoonmook Kang
JungYup Yang
spellingShingle MiJoung Kim
MoonHoe Kim
JungSeock Oh
NamHee Kwon
Yoonmook Kang
JungYup Yang
Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells
Sustainability
Perovskite photovoltaic devices
phenyl-C61-butyric acid methyl ester
MAPbI<sub>3</sub>
Efficiency
author_facet MiJoung Kim
MoonHoe Kim
JungSeock Oh
NamHee Kwon
Yoonmook Kang
JungYup Yang
author_sort MiJoung Kim
title Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells
title_short Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells
title_full Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells
title_fullStr Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells
title_full_unstemmed Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Perovskite Solar Cells
title_sort phenyl-c61-butyric acid methyl ester hybrid solution for efficient ch<sub>3</sub>nh<sub>3</sub>pbi<sub>3</sub> perovskite solar cells
publisher MDPI AG
series Sustainability
issn 2071-1050
publishDate 2019-07-01
description Organic&#8722;inorganic halide perovskite solar cells (PSCs) have excellent chemical, electronic, and optical properties, making them attractive next-generation thin-film solar cells. Typical PSCs were fabricated with a perovskite absorber layer between the TiO<sub>2</sub> electron-transport layer (ETL) and the 2,2&#8242;,7,7&#8242;-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9&#8242;-spirobifluorene (Spiro-OMeTAD) hole-transport layer (HTL). We examined the influence of phenyl-C61-butyric acid methyl ester (PCBM) on the PSC device. PSCs using the PCBM layer as an ETL were investigated, and the absorber layer was coated by dissolving PCBM in a methyl ammonium lead iodide (MAPbI<sub>3</sub>) precursor solution to examine the changes at the perovskite interface and inside the perovskite absorber layer. The PSCs fabricated by adding a small amount of PCBM to the MAPbI<sub>3</sub> solution exhibited a significantly higher maximum efficiency of 16.55% than conventional PSCs (14.34%). Fabricating the PCBM ETL and PCBM-MAPbI<sub>3</sub> hybrid solid is expected to be an efficient route for improving the photovoltaic performance.
topic Perovskite photovoltaic devices
phenyl-C61-butyric acid methyl ester
MAPbI<sub>3</sub>
Efficiency
url https://www.mdpi.com/2071-1050/11/14/3867
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