SOME NEW SULFATO AND HYDROGENOSULFATO ADDUCTS: SYNTHESIS, INFRARED AND MÖSSBAUER STUDIES

SOME NEW SULFATO AND HYDROGENOSULFATO ADDUCTS: SYNTHESIS, INFRARED AND MÖSSBAUER STUDIES

Eight organotin (IV) (mainly sulfato) adducts have been synthesized and studied by spectroscopic methods. While considering the anionic component, the suggested structures are discrete; supramolecular architectures are obtained with secondary interactions through NH----Cl and NH----O hydrogen bonds...

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Bibliographic Details
Main Authors: Alain Wattiaux, Umberto Russo, Libasse Diop, Lamine Diop, Kochikpa Y.A. Okio, Waly Diallo
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2010-07-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
organotin (IV) adducts
infrared
Mössbauer
ionic structures
hydrogen bonds
supramolecular architectures
tetrahedral SnMe2Cl2
Online Access:http://pubs.ub.ro/dwnl.php?id=CSCC6201011V02S01A0004
Description
Summary:Eight organotin (IV) (mainly sulfato) adducts have been synthesized and studied by spectroscopic methods. While considering the anionic component, the suggested structures are discrete; supramolecular architectures are obtained with secondary interactions through NH----Cl and NH----O hydrogen bonds while considering the cations, the anions behaving as monochelating, bridging or monocoordinating ligands, the environment around the tin (IV) centre being octahedral. Tetrahedral SnMe2Cl2 has been characterized spectroscopically.
ISSN:1582-540X

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