Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)

Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)

The title complex, [Ni(C12H11N2O2)2(C3H7NO)2], lies on on an inversion center. The NiII ion is coordinated in a slightly distorted octahedral coordination enviroment by four O atoms from two bis-chelating 4-acety-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in the equatorial plane and two O atoms fr...

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Main Authors: Hualing Zhu, Zhen Wei, Luxia Bu, Xiaoping Xu, Jun Shi
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810026231
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spelling doaj-67055d5afcc44247a316d6df5615851a2020-11-24T23:56:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m904m90410.1107/S1600536810026231Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)Hualing ZhuZhen WeiLuxia BuXiaoping XuJun ShiThe title complex, [Ni(C12H11N2O2)2(C3H7NO)2], lies on on an inversion center. The NiII ion is coordinated in a slightly distorted octahedral coordination enviroment by four O atoms from two bis-chelating 4-acety-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in the equatorial plane and two O atoms from two N,N-dimethylformamide ligands in the axial sites. In the crystal structure, weak intermolecular π–π stacking interactions with centroid–centroid distances of 3.7467 (13) Å link molecules into chains extending alongthe b axis. http://scripts.iucr.org/cgi-bin/paper?S1600536810026231
collection DOAJ
language English
format Article
sources DOAJ
author Hualing Zhu
Zhen Wei
Luxia Bu
Xiaoping Xu
Jun Shi
spellingShingle Hualing Zhu
Zhen Wei
Luxia Bu
Xiaoping Xu
Jun Shi
Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)
Acta Crystallographica Section E
author_facet Hualing Zhu
Zhen Wei
Luxia Bu
Xiaoping Xu
Jun Shi
author_sort Hualing Zhu
title Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)
title_short Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)
title_full Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)
title_fullStr Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)
title_full_unstemmed Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2O,O′)bis(N,N-dimethylformamide-κO)nickel(II)
title_sort bis(4-acetyl-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ2o,o′)bis(n,n-dimethylformamide-κo)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description The title complex, [Ni(C12H11N2O2)2(C3H7NO)2], lies on on an inversion center. The NiII ion is coordinated in a slightly distorted octahedral coordination enviroment by four O atoms from two bis-chelating 4-acety-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in the equatorial plane and two O atoms from two N,N-dimethylformamide ligands in the axial sites. In the crystal structure, weak intermolecular π–π stacking interactions with centroid–centroid distances of 3.7467 (13) Å link molecules into chains extending alongthe b axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810026231
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AT zhenwei bis4acetyl3methyl1phenyl1hpyrazol5olatoamp9542ooamp8242bisnndimethylformamideamp954onickelii
AT luxiabu bis4acetyl3methyl1phenyl1hpyrazol5olatoamp9542ooamp8242bisnndimethylformamideamp954onickelii
AT xiaopingxu bis4acetyl3methyl1phenyl1hpyrazol5olatoamp9542ooamp8242bisnndimethylformamideamp954onickelii
AT junshi bis4acetyl3methyl1phenyl1hpyrazol5olatoamp9542ooamp8242bisnndimethylformamideamp954onickelii
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