Crystal structure of 2,2-diphenylhydrazinium chloride

Crystal structure of 2,2-diphenylhydrazinium chloride

In the title compound, C12H13N2+·Cl−, the chloride salt of 1,1′-diphenylhydrazine, the phenyl rings are inclined to one another by 78.63 (17)°. The N—+NH3 bond lengths is 1.445 (3) Å, and the N—Cphenyl bond lengths are 1.435 (3) and 1.447 (4) Å. In the crystal, molecules are linked via N—H...Cl hydr...

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Bibliographic Details
Main Authors: Amit Kumal Paul, Soma Mukherjee, Helen Stoeckli-Evans
Format: Article
Language:English
Published: International Union of Crystallography 2014-11-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
diphenylhydrazine
hydrazinium
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814022879
Description
Summary:In the title compound, C12H13N2+·Cl−, the chloride salt of 1,1′-diphenylhydrazine, the phenyl rings are inclined to one another by 78.63 (17)°. The N—+NH3 bond lengths is 1.445 (3) Å, and the N—Cphenyl bond lengths are 1.435 (3) and 1.447 (4) Å. In the crystal, molecules are linked via N—H...Cl hydrogen bonds, forming chains along [10-1], which enclose two adjacent R42(6) ring motifs. The chains are reinforced by C—H...Cl hydrogen bonds.
ISSN:1600-5368

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