Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate

Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate

In the title compound, [Fe(C5H5)(C20H21N2O4)], the pyrrolidine ring exhibits an envelope conformation with the spiro-C atom deviating from the plane of the remaining four atoms. The pyrrolidine ring is almost perpendicular to the indolinone ring [dihedral angle = 87.52 (7)&#176...

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Main Authors: S. Kathiravan, R. Raghunathan, L. Sudha, S. Nirmala, E. Theboral Sugi Kamala
Format: Article
Language:English
Published: International Union of Crystallography 2009-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809012756
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spelling doaj-65ca7948be8149d4bbbdc0afa408fad82020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m531m53210.1107/S1600536809012756Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylateS. KathiravanR. RaghunathanL. SudhaS. NirmalaE. Theboral Sugi KamalaIn the title compound, [Fe(C5H5)(C20H21N2O4)], the pyrrolidine ring exhibits an envelope conformation with the spiro-C atom deviating from the plane of the remaining four atoms. The pyrrolidine ring is almost perpendicular to the indolinone ring [dihedral angle = 87.52 (7)°]. The structure is stabilized by an intramolecular O—H...N hydrogen bond and by intermolecular C—H...O and N—H...O interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536809012756
collection DOAJ
language English
format Article
sources DOAJ
author S. Kathiravan
R. Raghunathan
L. Sudha
S. Nirmala
E. Theboral Sugi Kamala
spellingShingle S. Kathiravan
R. Raghunathan
L. Sudha
S. Nirmala
E. Theboral Sugi Kamala
Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
Acta Crystallographica Section E
author_facet S. Kathiravan
R. Raghunathan
L. Sudha
S. Nirmala
E. Theboral Sugi Kamala
author_sort S. Kathiravan
title Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
title_short Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
title_full Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
title_fullStr Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
title_full_unstemmed Methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
title_sort methyl 3-[ferrocenyl(hydroxy)methyl]-1-methyl-2′-oxospiro[pyrrolidine-2,3′-indoline]-3-carboxylate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-05-01
description In the title compound, [Fe(C5H5)(C20H21N2O4)], the pyrrolidine ring exhibits an envelope conformation with the spiro-C atom deviating from the plane of the remaining four atoms. The pyrrolidine ring is almost perpendicular to the indolinone ring [dihedral angle = 87.52 (7)°]. The structure is stabilized by an intramolecular O—H...N hydrogen bond and by intermolecular C—H...O and N—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809012756
work_keys_str_mv AT skathiravan methyl3ferrocenylhydroxymethyl1methyl2amp8242oxospiropyrrolidine23amp8242indoline3carboxylate
AT rraghunathan methyl3ferrocenylhydroxymethyl1methyl2amp8242oxospiropyrrolidine23amp8242indoline3carboxylate
AT lsudha methyl3ferrocenylhydroxymethyl1methyl2amp8242oxospiropyrrolidine23amp8242indoline3carboxylate
AT snirmala methyl3ferrocenylhydroxymethyl1methyl2amp8242oxospiropyrrolidine23amp8242indoline3carboxylate
AT etheboralsugikamala methyl3ferrocenylhydroxymethyl1methyl2amp8242oxospiropyrrolidine23amp8242indoline3carboxylate
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