A Facile and Mild Synthesis of Trisubstituted Allylic Sulfones from Morita-Baylis-Hillman Carbonates

A Facile and Mild Synthesis of Trisubstituted Allylic Sulfones from Morita-Baylis-Hillman Carbonates

An efficient and catalyst-free synthesis of trisubstituted allylic sulfones through an allylic sulfonylation reaction of Morita-Baylis-Hillman (MBH) carbonates with sodium sulfinates has been developed. Under the optimized reaction conditions, a series of trisubstituted allylic sulfones were rapidly...

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Bibliographic Details
Main Authors: Lin Jiang, Yong-Gen Li, Jiang-Feng Zhou, Yong-Ming Chuan, Hong-Li Li, Ming-Long Yuan
Format: Article
Language:English
Published: MDPI AG 2015-05-01
Series:Molecules
Subjects:
Morita-Baylis-Hillman carbonate
allylic sulfone
trisubstituted alkene
allylic substitution
Online Access:http://www.mdpi.com/1420-3049/20/5/8213

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