Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties

Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties

The reaction between iron and nickel salts with ammonium salicylate results in the formation of a new trinuclear heterometallic complex [hexa-µ2-salicylato-µ3-oxo-(methanol)(dimethylformamide) aquadiiron(III) nickel(II)] methanol dimethylformamide. The synthesized [Fe2NiO(SalH)6(CH3OH)(DMF)(H2O)]•DM...

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Main Authors: Viorina Gorinchoy, Vera Zubareva, Elena Melnic, Victor Kravtsov
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2018-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
heterotrinuclear μ3-oxo complex
X-ray
IR analysis
Mössbauer spectrum
TG data
Online Access: http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.483-Gorinchoy.pdf
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spelling doaj-6582b350c3a443f0a522bfc2ec59fe3d2021-07-02T11:02:30ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882018-06-01131465310.19261/cjm.2018.483483Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical PropertiesViorina Gorinchoy0Vera Zubareva1Elena Melnic2Victor Kravtsov3 Institute of Chemistry, 3, Academiei str., Chisinau MD 2028, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD 2028, Republic of Moldova Institute of Applied Physics, 5, Academiei str., Chisinau MD 2028, Republic of Moldova Institute of Applied Physics, 5, Academiei str., Chisinau MD 2028, Republic of Moldova The reaction between iron and nickel salts with ammonium salicylate results in the formation of a new trinuclear heterometallic complex [hexa-µ2-salicylato-µ3-oxo-(methanol)(dimethylformamide) aquadiiron(III) nickel(II)] methanol dimethylformamide. The synthesized [Fe2NiO(SalH)6(CH3OH)(DMF)(H2O)]•DMF•CH3OH complex crystallizes in the monoclinic space group C2/c. The IR and Mössbauer spectra and thermal properties were studied. http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.483-Gorinchoy.pdf heterotrinuclear μ3-oxo complexX-rayIR analysisMössbauer spectrumTG data
collection DOAJ
language English
format Article
sources DOAJ
author Viorina Gorinchoy
Vera Zubareva
Elena Melnic
Victor Kravtsov
spellingShingle Viorina Gorinchoy
Vera Zubareva
Elena Melnic
Victor Kravtsov
Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
heterotrinuclear μ3-oxo complex
X-ray
IR analysis
Mössbauer spectrum
TG data
author_facet Viorina Gorinchoy
Vera Zubareva
Elena Melnic
Victor Kravtsov
author_sort Viorina Gorinchoy
title Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties
title_short Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties
title_full Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties
title_fullStr Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties
title_full_unstemmed Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties
title_sort heterotrinuclear [fe2iiiniii]-µ3-oxo-cluster based on salicylic acid. synthesis, structure and physico-chemical properties
publisher Academy of Sciences of Moldova, Institute of Chemistry
series Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
issn 1857-1727
2345-1688
publishDate 2018-06-01
description The reaction between iron and nickel salts with ammonium salicylate results in the formation of a new trinuclear heterometallic complex [hexa-µ2-salicylato-µ3-oxo-(methanol)(dimethylformamide) aquadiiron(III) nickel(II)] methanol dimethylformamide. The synthesized [Fe2NiO(SalH)6(CH3OH)(DMF)(H2O)]•DMF•CH3OH complex crystallizes in the monoclinic space group C2/c. The IR and Mössbauer spectra and thermal properties were studied.
topic heterotrinuclear μ3-oxo complex
X-ray
IR analysis
Mössbauer spectrum
TG data
url http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.483-Gorinchoy.pdf
work_keys_str_mv AT viorinagorinchoy heterotrinuclearfe2iiiniiiμ3oxoclusterbasedonsalicylicacidsynthesisstructureandphysicochemicalproperties
AT verazubareva heterotrinuclearfe2iiiniiiμ3oxoclusterbasedonsalicylicacidsynthesisstructureandphysicochemicalproperties
AT elenamelnic heterotrinuclearfe2iiiniiiμ3oxoclusterbasedonsalicylicacidsynthesisstructureandphysicochemicalproperties
AT victorkravtsov heterotrinuclearfe2iiiniiiμ3oxoclusterbasedonsalicylicacidsynthesisstructureandphysicochemicalproperties
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