Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties

Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster Based on Salicylic Acid. Synthesis, Structure and Physico-chemical Properties

The reaction between iron and nickel salts with ammonium salicylate results in the formation of a new trinuclear heterometallic complex [hexa-µ2-salicylato-µ3-oxo-(methanol)(dimethylformamide) aquadiiron(III) nickel(II)] methanol dimethylformamide. The synthesized [Fe2NiO(SalH)6(CH3OH)(DMF)(H2O)]•DM...

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Bibliographic Details
Main Authors: Viorina Gorinchoy, Vera Zubareva, Elena Melnic, Victor Kravtsov
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2018-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
heterotrinuclear μ3-oxo complex
X-ray
IR analysis
Mössbauer spectrum
TG data
Online Access: http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.483-Gorinchoy.pdf
Description
Summary:The reaction between iron and nickel salts with ammonium salicylate results in the formation of a new trinuclear heterometallic complex [hexa-µ2-salicylato-µ3-oxo-(methanol)(dimethylformamide) aquadiiron(III) nickel(II)] methanol dimethylformamide. The synthesized [Fe2NiO(SalH)6(CH3OH)(DMF)(H2O)]•DMF•CH3OH complex crystallizes in the monoclinic space group C2/c. The IR and Mössbauer spectra and thermal properties were studied.
ISSN:1857-1727
2345-1688

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