The structural characterisation of HWCVD-deposited nanocrystalline silicon films

Nanocrystalline silicon (nc-Si) films were deposited by hot-wire chemical vapour deposition (HWCVD) in the presence of varying H2 concentrations and their structural and interfacial character investigated by X-ray diffraction, small-angle X-ray scattering (SAXS) and Raman spectroscopy. The crystalli...

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Bibliographic Details
Main Author: Bibhu P. Swain
Format: Article
Language:English
Published: Academy of Science of South Africa 2009-12-01
Series:South African Journal of Science
Online Access:http://archive.sajs.co.za/index.php/SAJS/article/view/41
Description
Summary:Nanocrystalline silicon (nc-Si) films were deposited by hot-wire chemical vapour deposition (HWCVD) in the presence of varying H2 concentrations and their structural and interfacial character investigated by X-ray diffraction, small-angle X-ray scattering (SAXS) and Raman spectroscopy. The crystalline fraction was around 30–50% and the nc-Si crystallite size was in the range 20–35 nm. The SAXS results were analysed by Guinier plot, scaling factor, and correlation distance. The nc-Si grains displayed a mass fractal appearance, and the interfacial inhomogeneity distance was ~2 nm.
ISSN:0038-2353
1996-7489