Nature of Heat and Thermal Energy: From Caloric to Carnot’s Reflections, to Entropy, Exergy, Entransy and Beyond

The nature of thermal phenomena is still elusive and sometimes misconstrued. Starting from Lavoisier, who presumed that caloric as a weightless substance is conserved, to Sadi Carnot who erroneously assumed that work is extracted while caloric is conserved, to modern day researchers who argue that t...

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Bibliographic Details
Main Author: Milivoje M. Kostic
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/20/8/584
Description
Summary:The nature of thermal phenomena is still elusive and sometimes misconstrued. Starting from Lavoisier, who presumed that caloric as a weightless substance is conserved, to Sadi Carnot who erroneously assumed that work is extracted while caloric is conserved, to modern day researchers who argue that thermal energy is an indistinguishable part of internal energy, to the generalization of entropy and challengers of the Second Law of thermodynamics, the relevant thermal concepts are critically discussed here. Original reflections about the nature of thermo-mechanical energy transfer, classical and generalized entropy, exergy, and new entransy concept are reasoned and put in historical and contemporary contexts, with the objective of promoting further constructive debates and hopefully resolve some critical issues within the subtle thermal landscape.
ISSN:1099-4300