Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate

Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate

In the title compound, 2C12H20N22+·2H3O+·P6O186−·2H2O, a protonated water molecule bridges the centrosymmetrical anionic P6O18 ring via O—H...O hydrogen bonds. The centrosymmetric hydrogen-bonded rings formed by four oxonium cations and four phosphate a...

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Main Authors: Iness Ameur, Sonia Abid, Salem S Al-Deyab, Mohamed Rzaigui
Format: Article
Language:English
Published: International Union of Crystallography 2013-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813016759
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spelling doaj-648f83b310414ee4b82fdc2e592493502020-11-25T00:20:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697o1145o114610.1107/S1600536813016759Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrateIness AmeurSonia AbidSalem S Al-DeyabMohamed RzaiguiIn the title compound, 2C12H20N22+·2H3O+·P6O186−·2H2O, a protonated water molecule bridges the centrosymmetrical anionic P6O18 ring via O—H...O hydrogen bonds. The centrosymmetric hydrogen-bonded rings formed by four oxonium cations and four phosphate anions can be described by an R48(36) graph-set motif. The ring motifs are connected by hydrogen bonds into inorganic layers perpendicular to [100]. The 1-(2,3-dimethylphenyl)piperazine-1,4-diium cations are located between the layers, compensating their negative charge and establishing N—H...O hydrogen bonds with the O atoms of the anionic framework.http://scripts.iucr.org/cgi-bin/paper?S1600536813016759
collection DOAJ
language English
format Article
sources DOAJ
author Iness Ameur
Sonia Abid
Salem S Al-Deyab
Mohamed Rzaigui
spellingShingle Iness Ameur
Sonia Abid
Salem S Al-Deyab
Mohamed Rzaigui
Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
Acta Crystallographica Section E
author_facet Iness Ameur
Sonia Abid
Salem S Al-Deyab
Mohamed Rzaigui
author_sort Iness Ameur
title Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
title_short Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
title_full Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
title_fullStr Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
title_full_unstemmed Bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
title_sort bis[1-(2,3-dimethylphenyl)piperazine-1,4-diium] bis(oxonium) cyclohexaphosphate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-07-01
description In the title compound, 2C12H20N22+·2H3O+·P6O186−·2H2O, a protonated water molecule bridges the centrosymmetrical anionic P6O18 ring via O—H...O hydrogen bonds. The centrosymmetric hydrogen-bonded rings formed by four oxonium cations and four phosphate anions can be described by an R48(36) graph-set motif. The ring motifs are connected by hydrogen bonds into inorganic layers perpendicular to [100]. The 1-(2,3-dimethylphenyl)piperazine-1,4-diium cations are located between the layers, compensating their negative charge and establishing N—H...O hydrogen bonds with the O atoms of the anionic framework.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813016759
work_keys_str_mv AT inessameur bis123dimethylphenylpiperazine14diiumbisoxoniumcyclohexaphosphatedihydrate
AT soniaabid bis123dimethylphenylpiperazine14diiumbisoxoniumcyclohexaphosphatedihydrate
AT salemsaldeyab bis123dimethylphenylpiperazine14diiumbisoxoniumcyclohexaphosphatedihydrate
AT mohamedrzaigui bis123dimethylphenylpiperazine14diiumbisoxoniumcyclohexaphosphatedihydrate
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