1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione

1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione

The title compound, C22H17ClN2O2, crystallizes with two independent molecules (A and B) in the asymmetric unit. The 6-chloroquinoxaline-2,3(1H,4H)-dione ring system is essentially planar. The dihedral angles between the mean planes of the 6-chloroquinoxaline-2,3(1H,4H)-dione ring and the phenyl ring...

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Main Authors: Ali El Janati, Youssef Kandri Rodi, Jerry P. Jasinski, Manpreet Kaur, Younes Ouzidan, El Mokhtar Essassi
Format: Article
Language:English
Published: International Union of Crystallography 2017-06-01
Series:IUCrData
Subjects:
crystal structure
quinoxaline
alkylation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617009014
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spelling doaj-63c156df8fcf405b8d89d1447c739c052020-11-24T23:41:26ZengInternational Union of CrystallographyIUCrData2414-31462017-06-0126x17090110.1107/S2414314617009014sj41231,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dioneAli El Janati0Youssef Kandri Rodi1Jerry P. Jasinski2Manpreet Kaur3Younes Ouzidan4El Mokhtar Essassi5Laboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoLaboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoDepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USADepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USALaboratoire de Chimie Organique Appliquée, Faculté des Sciences et Techniques, Université Sidi Mohammed Ben Abdellah, Fès, MoroccoLaboratoire de Chimie Organique Hétérocyclique, Pôle de Compétences Pharmacochimie, Mohammed V University in Rabat, BP 1014, Avenue Ibn Batouta, Rabat, MoroccoThe title compound, C22H17ClN2O2, crystallizes with two independent molecules (A and B) in the asymmetric unit. The 6-chloroquinoxaline-2,3(1H,4H)-dione ring system is essentially planar. The dihedral angles between the mean planes of the 6-chloroquinoxaline-2,3(1H,4H)-dione ring and the phenyl rings of the benzyl substituents in the two molecules are 68.34 and 73.8 (7)° for A, and 73.8 (5) and 80.7 (1)° for B, so that these rings point away from the quinoxaline ring system. In the crystal, weak C—H...O hydrogen bonds and π–π stacking interactions link the molecules into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2414314617009014crystal structurequinoxalinealkylation
collection DOAJ
language English
format Article
sources DOAJ
author Ali El Janati
Youssef Kandri Rodi
Jerry P. Jasinski
Manpreet Kaur
Younes Ouzidan
El Mokhtar Essassi
spellingShingle Ali El Janati
Youssef Kandri Rodi
Jerry P. Jasinski
Manpreet Kaur
Younes Ouzidan
El Mokhtar Essassi
1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione
IUCrData
crystal structure
quinoxaline
alkylation
author_facet Ali El Janati
Youssef Kandri Rodi
Jerry P. Jasinski
Manpreet Kaur
Younes Ouzidan
El Mokhtar Essassi
author_sort Ali El Janati
title 1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione
title_short 1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione
title_full 1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione
title_fullStr 1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione
title_full_unstemmed 1,4-Dibenzyl-6-chloroquinoxaline-2,3(1H,4H)-dione
title_sort 1,4-dibenzyl-6-chloroquinoxaline-2,3(1h,4h)-dione
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2017-06-01
description The title compound, C22H17ClN2O2, crystallizes with two independent molecules (A and B) in the asymmetric unit. The 6-chloroquinoxaline-2,3(1H,4H)-dione ring system is essentially planar. The dihedral angles between the mean planes of the 6-chloroquinoxaline-2,3(1H,4H)-dione ring and the phenyl rings of the benzyl substituents in the two molecules are 68.34 and 73.8 (7)° for A, and 73.8 (5) and 80.7 (1)° for B, so that these rings point away from the quinoxaline ring system. In the crystal, weak C—H...O hydrogen bonds and π–π stacking interactions link the molecules into a three-dimensional network.
topic crystal structure
quinoxaline
alkylation
url http://scripts.iucr.org/cgi-bin/paper?S2414314617009014
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AT jerrypjasinski 14dibenzyl6chloroquinoxaline231h4hdione
AT manpreetkaur 14dibenzyl6chloroquinoxaline231h4hdione
AT younesouzidan 14dibenzyl6chloroquinoxaline231h4hdione
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