Sulfonated Cellulose-Based Magnetic Composite as Useful Media for Water Remediation from Amine Pollutants

Commercially available microcrystalline cellulose (MCC) was functionalized using chlorosulfonic acid, while iron oxide nanoparticles (IONPs) were adsorbed on the surface of the cellulose derivative by the Massart’s co-precipitation method. The obtained magnetite-decorated sulfate cellulose nanoparti...

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Bibliographic Details
Main Authors: Antonio De Nino, Matteo Antonio Tallarida, Vincenzo Algieri, Fabrizio Olivito, Paola Costanzo, Giovanni De Filpo, Loredana Maiuolo
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/10/22/8155
Description
Summary:Commercially available microcrystalline cellulose (MCC) was functionalized using chlorosulfonic acid, while iron oxide nanoparticles (IONPs) were adsorbed on the surface of the cellulose derivative by the Massart’s co-precipitation method. The obtained magnetite-decorated sulfate cellulose nanoparticles (MDSCNs) were characterized via Fourier transform infrared (FTIR) spectroscopy, scanning-electron microscopy (SEM), and elemental analysis, while the acidity of the functionalized cellulose was determined using an acid–base titration with phenolphthalein as an indicator. Furthermore, in order to determine the adsorptive power of the obtained composite, a series of analyses were performed on aqueous amine pollutants using flame ionization detection gas chromatography (GC-FID). The results of this study clearly show how a bio-compatible green polymer as cellulose can be easy functionalized in order to improve its chemical and physical properties, obtaining a magnetic composite useful in water purification. Adsorption percentages up to 90% and a very small amount of composite used (100 mg) proved how our material can be a powerful tool in environmental remediation.
ISSN:2076-3417