Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]

Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]

The title compound, [Cu2V4O12(C10H8N2)2]n, shows a two-dimensional copper–vanadate layer composed of eight-membered rings, each containing four corner-sharing VO4 tetrahedra; these are linked through six pentacoordinated CuII atoms with the 2,2′-bipyridine ligands attached and po...

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Main Authors: Chao Yang, Zhihui Yi, Xianzhu Xu, Wujiong Xia, Xiao Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807067979
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spelling doaj-638ad9d5af084139ab6fb34399d440a62020-11-25T02:46:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m287m28810.1107/S1600536807067979Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]Chao YangZhihui YiXianzhu XuWujiong XiaXiao ZhangThe title compound, [Cu2V4O12(C10H8N2)2]n, shows a two-dimensional copper–vanadate layer composed of eight-membered rings, each containing four corner-sharing VO4 tetrahedra; these are linked through six pentacoordinated CuII atoms with the 2,2′-bipyridine ligands attached and pointing above and below the plane of the layer. The Cu atom is coordinated by two N donors from the 2,2′-bipyridine ligand and three O atoms from three adjacent VO4 units to form a distorted tetragonal pyramid. These layers are further connected by π–π interactions between interleaving bipyridine ligands of adjacent layers [centroid–centroid distances = 3.63 (1) and 3.68 (1) Å] into a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536807067979
collection DOAJ
language English
format Article
sources DOAJ
author Chao Yang
Zhihui Yi
Xianzhu Xu
Wujiong Xia
Xiao Zhang
spellingShingle Chao Yang
Zhihui Yi
Xianzhu Xu
Wujiong Xia
Xiao Zhang
Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
Acta Crystallographica Section E
author_facet Chao Yang
Zhihui Yi
Xianzhu Xu
Wujiong Xia
Xiao Zhang
author_sort Chao Yang
title Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
title_short Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
title_full Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
title_fullStr Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
title_full_unstemmed Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
title_sort poly[bis(2,2′-bipyridine-κ2n,n′)deca-μ-oxido-dioxidodicopper(ii)tetravanadium(v)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description The title compound, [Cu2V4O12(C10H8N2)2]n, shows a two-dimensional copper–vanadate layer composed of eight-membered rings, each containing four corner-sharing VO4 tetrahedra; these are linked through six pentacoordinated CuII atoms with the 2,2′-bipyridine ligands attached and pointing above and below the plane of the layer. The Cu atom is coordinated by two N donors from the 2,2′-bipyridine ligand and three O atoms from three adjacent VO4 units to form a distorted tetragonal pyramid. These layers are further connected by π–π interactions between interleaving bipyridine ligands of adjacent layers [centroid–centroid distances = 3.63 (1) and 3.68 (1) Å] into a three-dimensional supramolecular structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807067979
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AT zhihuiyi polybis228242bipyridine9542nn8242deca956oxidodioxidodicopperiitetravanadiumv
AT xianzhuxu polybis228242bipyridine9542nn8242deca956oxidodioxidodicopperiitetravanadiumv
AT wujiongxia polybis228242bipyridine9542nn8242deca956oxidodioxidodicopperiitetravanadiumv
AT xiaozhang polybis228242bipyridine9542nn8242deca956oxidodioxidodicopperiitetravanadiumv
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