Poly[bis(2,2′-bipyridine-κ2N,N′)deca-μ-oxido-dioxidodicopper(II)tetravanadium(V)]
The title compound, [Cu2V4O12(C10H8N2)2]n, shows a two-dimensional copper–vanadate layer composed of eight-membered rings, each containing four corner-sharing VO4 tetrahedra; these are linked through six pentacoordinated CuII atoms with the 2,2′-bipyridine ligands attached and po...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807067979 |
| Summary: | The title compound, [Cu2V4O12(C10H8N2)2]n, shows a two-dimensional copper–vanadate layer composed of eight-membered rings, each containing four corner-sharing VO4 tetrahedra; these are linked through six pentacoordinated CuII atoms with the 2,2′-bipyridine ligands attached and pointing above and below the plane of the layer. The Cu atom is coordinated by two N donors from the 2,2′-bipyridine ligand and three O atoms from three adjacent VO4 units to form a distorted tetragonal pyramid. These layers are further connected by π–π interactions between interleaving bipyridine ligands of adjacent layers [centroid–centroid distances = 3.63 (1) and 3.68 (1) Å] into a three-dimensional supramolecular structure. |
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| ISSN: | 1600-5368 |