Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)

Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)

In the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting (iPr2NH2+)2·C2O42− with SnI4 in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the cryst...

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Main Authors: Bougar Sarr, Cheikh Abdoul Khadir Diop, Mamadou Sidibé, Yoann Rousselin
Format: Article
Language:English
Published: International Union of Crystallography 2018-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
tin(IV) oxalate
N—H...O hydrogen bonding
bifurcated N—H...(O,O) hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018003602
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spelling doaj-638076c45a974d1d840319742519dd282020-11-24T23:28:17ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-04-0174450250410.1107/S2056989018003602hb7738Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)Bougar Sarr0Cheikh Abdoul Khadir Diop1Mamadou Sidibé2Yoann Rousselin3Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Téchniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Téchniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Téchniques, Université Cheikh Anta Diop, Dakar, SenegalICMUB, UMR CNRS 6302, Universite Bourgogne Franche Comte, 9 avenue Alain Savary, 21078 Dijon cedex, FranceIn the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting (iPr2NH2+)2·C2O42− with SnI4 in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H...O and bifurcated N—H...(O,O) hydrogen bonds, generating [10-1] chains.http://scripts.iucr.org/cgi-bin/paper?S2056989018003602crystal structuretin(IV) oxalateN—H...O hydrogen bondingbifurcated N—H...(O,O) hydrogen bonds
collection DOAJ
language English
format Article
sources DOAJ
author Bougar Sarr
Cheikh Abdoul Khadir Diop
Mamadou Sidibé
Yoann Rousselin
spellingShingle Bougar Sarr
Cheikh Abdoul Khadir Diop
Mamadou Sidibé
Yoann Rousselin
Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
tin(IV) oxalate
N—H...O hydrogen bonding
bifurcated N—H...(O,O) hydrogen bonds
author_facet Bougar Sarr
Cheikh Abdoul Khadir Diop
Mamadou Sidibé
Yoann Rousselin
author_sort Bougar Sarr
title Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)
title_short Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)
title_full Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)
title_fullStr Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)
title_full_unstemmed Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV)
title_sort crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2o1,o2)stannate(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2018-04-01
description In the title compound, (iPr2NH2)2[SnI2(C2O4)2], which was prepared by reacting (iPr2NH2+)2·C2O42− with SnI4 in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H...O and bifurcated N—H...(O,O) hydrogen bonds, generating [10-1] chains.
topic crystal structure
tin(IV) oxalate
N—H...O hydrogen bonding
bifurcated N—H...(O,O) hydrogen bonds
url http://scripts.iucr.org/cgi-bin/paper?S2056989018003602
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