(5E)-5-(4-Hydroxy-3-methoxybenzylidene)-2-thioxo-1,3-thiazolidin-4-one methanol monosolvate

In the title compound, C11H9NO3S2·CH4O, the dihedral angle between the aromatic rings is 3.57 (16)° and intramolecular O—H...O and C—H...S interactions occur. In the crystal, the thiazolidin-4-one molecules are linked by N&#...

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Bibliographic Details
Main Authors: Durre Shahwar, M. Nawaz Tahir, Muhammad Asam Raza, Maria Saddaf, Sana Majeed
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809039567
Description
Summary:In the title compound, C11H9NO3S2·CH4O, the dihedral angle between the aromatic rings is 3.57 (16)° and intramolecular O—H...O and C—H...S interactions occur. In the crystal, the thiazolidin-4-one molecules are linked by N—H...O hydrogen bonds, forming chains. The hydrogen-bond motifs lead to S(5), S(6) and R33(8) ring motifs. There exist C=O...π interactions between the heterocyclic rings and π–π interactions between the heterocyclic and benzene rings at distances of 3.455 (2) and 3.602 (2) Å, respectively. The methanol solvent molecule is disordered over two sets of sites in a 0.542 (9):0.458 (9) ratio.
ISSN:1600-5368