Bis(guanidinium) tetraiodidomercurate(II)

Bis(guanidinium) tetraiodidomercurate(II)

The Hg atom in the crystal structure of the title compound, (CH6N3)2[HgI4], is tetrahedrally coordinated by four I atoms. The [HgI4]2− ions are interconnected to the [C(NH2)3]+ ions by N—H...I hydrogen bonds, forming a three-dimensional network. The four different observe...

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Main Authors: B. Thimme Gowda, Yoshihiro Furukawa, Hideta Ishihara, Thorsten M. Gesing, Hiromitsu Terao
Format: Article
Language:English
Published: International Union of Crystallography 2009-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680901280X
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spelling doaj-631a1c9f8e524804b09db1acc744a61e2020-11-25T02:40:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m503m50310.1107/S160053680901280XBis(guanidinium) tetraiodidomercurate(II)B. Thimme GowdaYoshihiro FurukawaHideta IshiharaThorsten M. GesingHiromitsu TeraoThe Hg atom in the crystal structure of the title compound, (CH6N3)2[HgI4], is tetrahedrally coordinated by four I atoms. The [HgI4]2− ions are interconnected to the [C(NH2)3]+ ions by N—H...I hydrogen bonds, forming a three-dimensional network. The four different observed Hg—I distances [2.760 (2), 2.7762 (15), 2.8098 (14) and 2.833 (2) Å] are consistent with four different 127I NQR frequencies observed, showing the existence of four unique I atoms in the tetraiodidomercurate unit. http://scripts.iucr.org/cgi-bin/paper?S160053680901280X
collection DOAJ
language English
format Article
sources DOAJ
author B. Thimme Gowda
Yoshihiro Furukawa
Hideta Ishihara
Thorsten M. Gesing
Hiromitsu Terao
spellingShingle B. Thimme Gowda
Yoshihiro Furukawa
Hideta Ishihara
Thorsten M. Gesing
Hiromitsu Terao
Bis(guanidinium) tetraiodidomercurate(II)
Acta Crystallographica Section E
author_facet B. Thimme Gowda
Yoshihiro Furukawa
Hideta Ishihara
Thorsten M. Gesing
Hiromitsu Terao
author_sort B. Thimme Gowda
title Bis(guanidinium) tetraiodidomercurate(II)
title_short Bis(guanidinium) tetraiodidomercurate(II)
title_full Bis(guanidinium) tetraiodidomercurate(II)
title_fullStr Bis(guanidinium) tetraiodidomercurate(II)
title_full_unstemmed Bis(guanidinium) tetraiodidomercurate(II)
title_sort bis(guanidinium) tetraiodidomercurate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-05-01
description The Hg atom in the crystal structure of the title compound, (CH6N3)2[HgI4], is tetrahedrally coordinated by four I atoms. The [HgI4]2− ions are interconnected to the [C(NH2)3]+ ions by N—H...I hydrogen bonds, forming a three-dimensional network. The four different observed Hg—I distances [2.760 (2), 2.7762 (15), 2.8098 (14) and 2.833 (2) Å] are consistent with four different 127I NQR frequencies observed, showing the existence of four unique I atoms in the tetraiodidomercurate unit.
url http://scripts.iucr.org/cgi-bin/paper?S160053680901280X
work_keys_str_mv AT bthimmegowda bisguanidiniumtetraiodidomercurateii
AT yoshihirofurukawa bisguanidiniumtetraiodidomercurateii
AT hidetaishihara bisguanidiniumtetraiodidomercurateii
AT thorstenmgesing bisguanidiniumtetraiodidomercurateii
AT hiromitsuterao bisguanidiniumtetraiodidomercurateii
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