Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt

The utilization of nanomaterials in the field of binder materials for road paving has attracted researchers’ attention in recent years. This study presented the performance properties of a binder modified with carbon nanotubes (CNT) and polyethylene (PE). The rheological properties, adhesion behavio...

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Main Authors: Ming Liang, Linping Su, Peizhao Li, Jingtao Shi, Zhanyong Yao, Jizhe Zhang, Hongguang Jiang, Weixin Luo
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/18/4077
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spelling doaj-630ed2361b094d3e902844054a73b0ea2020-11-25T01:26:23ZengMDPI AGMaterials1996-19442020-09-01134077407710.3390/ma13184077Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified AsphaltMing Liang0Linping Su1Peizhao Li2Jingtao Shi3Zhanyong Yao4Jizhe Zhang5Hongguang Jiang6Weixin Luo7School of Qilu Transportation, Shandong University, Jinan 250002, ChinaSchool of Qilu Transportation, Shandong University, Jinan 250002, ChinaSchool of Qilu Transportation, Shandong University, Jinan 250002, ChinaPetroChina Fuel Oil Co., Ltd., Research Institute, Beijing 100195, ChinaSchool of Qilu Transportation, Shandong University, Jinan 250002, ChinaSchool of Qilu Transportation, Shandong University, Jinan 250002, ChinaSchool of Qilu Transportation, Shandong University, Jinan 250002, ChinaState Key Laboratory of Special Functional Waterproof Materials, Beijing Oriental Yuhong Waterproof Technology Co. Ltd., Beijing 100123, ChinaThe utilization of nanomaterials in the field of binder materials for road paving has attracted researchers’ attention in recent years. This study presented the performance properties of a binder modified with carbon nanotubes (CNT) and polyethylene (PE). The rheological properties, adhesion behavior, morphology, and storage stability of the modified asphalt were investigated. Experimental analysis indicated a positive effect of CNT/PE composites on the performance of the binder. The results indicate that the combined use of CNT and PE shows a significant enhancement on complex modulus, viscosity, and creep recovery of the binder at high temperatures and a great decrease in compliance, indicating great resistance to permanent deformation. Meanwhile, only using CNT to improve the high temperature performance of the binder is limited due to high shear mixing. CNT/PE modifiers enhance the cracking resistance at low temperatures and moisture damage resistance. The CNT/PE melt mixing composites endow asphalt with stronger cracking resistance, better resistance to moisture damage and workability. Asphalt with CNT/PE composites formed an even dispersion system. Notably, CNT bridges on the interface between PE phase and asphalt for the two modified asphalts, which reinforces the cohesion of interface. Asphalt with CNT/PE composites showed improved storage stability in comparison with PE modified asphalt.https://www.mdpi.com/1996-1944/13/18/4077modified asphaltcarbon nanotubepolyethylenerheological propertiesmicro-morphologies
collection DOAJ
language English
format Article
sources DOAJ
author Ming Liang
Linping Su
Peizhao Li
Jingtao Shi
Zhanyong Yao
Jizhe Zhang
Hongguang Jiang
Weixin Luo
spellingShingle Ming Liang
Linping Su
Peizhao Li
Jingtao Shi
Zhanyong Yao
Jizhe Zhang
Hongguang Jiang
Weixin Luo
Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt
Materials
modified asphalt
carbon nanotube
polyethylene
rheological properties
micro-morphologies
author_facet Ming Liang
Linping Su
Peizhao Li
Jingtao Shi
Zhanyong Yao
Jizhe Zhang
Hongguang Jiang
Weixin Luo
author_sort Ming Liang
title Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt
title_short Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt
title_full Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt
title_fullStr Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt
title_full_unstemmed Investigating the Rheological Properties of Carbon Nanotubes/Polymer Composites Modified Asphalt
title_sort investigating the rheological properties of carbon nanotubes/polymer composites modified asphalt
publisher MDPI AG
series Materials
issn 1996-1944
publishDate 2020-09-01
description The utilization of nanomaterials in the field of binder materials for road paving has attracted researchers’ attention in recent years. This study presented the performance properties of a binder modified with carbon nanotubes (CNT) and polyethylene (PE). The rheological properties, adhesion behavior, morphology, and storage stability of the modified asphalt were investigated. Experimental analysis indicated a positive effect of CNT/PE composites on the performance of the binder. The results indicate that the combined use of CNT and PE shows a significant enhancement on complex modulus, viscosity, and creep recovery of the binder at high temperatures and a great decrease in compliance, indicating great resistance to permanent deformation. Meanwhile, only using CNT to improve the high temperature performance of the binder is limited due to high shear mixing. CNT/PE modifiers enhance the cracking resistance at low temperatures and moisture damage resistance. The CNT/PE melt mixing composites endow asphalt with stronger cracking resistance, better resistance to moisture damage and workability. Asphalt with CNT/PE composites formed an even dispersion system. Notably, CNT bridges on the interface between PE phase and asphalt for the two modified asphalts, which reinforces the cohesion of interface. Asphalt with CNT/PE composites showed improved storage stability in comparison with PE modified asphalt.
topic modified asphalt
carbon nanotube
polyethylene
rheological properties
micro-morphologies
url https://www.mdpi.com/1996-1944/13/18/4077
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