μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate

μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate

In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear RuII complex dication, [{RuCl(η6-cym)}2(μ-tape)]2+, built up by a planar 1,6,7,12-tetraazaperylene (tape) bridge, two η6-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The RuII atom show...

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Main Authors: Thomas Brietzke, Daniel Kässler, Alexandra Kelling, Uwe Schilde, Hans-Jürgen Holdt
Format: Article
Language:English
Published: International Union of Crystallography 2014-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681400035X
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spelling doaj-62113d6f50cd46df9c88255d09f9d14b2020-11-25T02:00:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702m39m4010.1107/S160053681400035Xtk5277μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvateThomas Brietzke0Daniel Kässler1Alexandra Kelling2Uwe Schilde3Hans-Jürgen Holdt4Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, GermanyUniversität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, GermanyUniversität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, GermanyUniversität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, GermanyUniversität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, GermanyIn the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear RuII complex dication, [{RuCl(η6-cym)}2(μ-tape)]2+, built up by a planar 1,6,7,12-tetraazaperylene (tape) bridge, two η6-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The RuII atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexafluoridophosphate anion and the asymmetric unit is completed by an acetone molecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C—H...O/F/Cl interactions.http://scripts.iucr.org/cgi-bin/paper?S160053681400035X
collection DOAJ
language English
format Article
sources DOAJ
author Thomas Brietzke
Daniel Kässler
Alexandra Kelling
Uwe Schilde
Hans-Jürgen Holdt
spellingShingle Thomas Brietzke
Daniel Kässler
Alexandra Kelling
Uwe Schilde
Hans-Jürgen Holdt
μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
Acta Crystallographica Section E
author_facet Thomas Brietzke
Daniel Kässler
Alexandra Kelling
Uwe Schilde
Hans-Jürgen Holdt
author_sort Thomas Brietzke
title μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
title_short μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
title_full μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
title_fullStr μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
title_full_unstemmed μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
title_sort μ-1,6,7,12-tetraazaperylene-κ4n1,n12:n6,n7-bis[chlorido(η6-p-cymene)ruthenium(ii)] bis(hexafluoridophosphate) acetone disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-02-01
description In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear RuII complex dication, [{RuCl(η6-cym)}2(μ-tape)]2+, built up by a planar 1,6,7,12-tetraazaperylene (tape) bridge, two η6-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The RuII atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexafluoridophosphate anion and the asymmetric unit is completed by an acetone molecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C—H...O/F/Cl interactions.
url http://scripts.iucr.org/cgi-bin/paper?S160053681400035X
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