4-Hydroxy-3-(3-methoxybenzoyl)-2-[(3-methoxybenzoyl)methyl]-2H-1,2-benzothiazine 1,1-dioxide

In the title compound, C25H21NO7S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; th...

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Bibliographic Details
Main Authors: Salman Gul, Hamid Latif Siddiqui, Matloob Ahmad, Muhammad Nisar, Masood Parvez
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810031673
Description
Summary:In the title compound, C25H21NO7S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; the puckering parameters are: Q = 0.4576 (13) Å, θ = 58.6 (2) and ϕ = 34.3 (3)°. The structure is devoid of any classical hydrogen bonds. However, intramolecular C—H...N and O—H...O hydrogen bonds result in six-membered rings and intermolecular C—H...O interactions stabilize the crystal structure.
ISSN:1600-5368