catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]

catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]

In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)]n, the CuI atom is coordinated in a distorted tetrahedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thiocyanate anions. The thiocyanate anion bridges the CuI ato...

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Main Authors: Aliakbar Dehno Khalaji, Hassan Hadadzadeh, Kazuma Gotoh, Hiroyuki Ishida
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808041925
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spelling doaj-616b98f93de04003a34682011bc937502020-11-25T00:48:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m70m7010.1107/S1600536808041925catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]Aliakbar Dehno KhalajiHassan HadadzadehKazuma GotohHiroyuki IshidaIn the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)]n, the CuI atom is coordinated in a distorted tetrahedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thiocyanate anions. The thiocyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.http://scripts.iucr.org/cgi-bin/paper?S1600536808041925
collection DOAJ
language English
format Article
sources DOAJ
author Aliakbar Dehno Khalaji
Hassan Hadadzadeh
Kazuma Gotoh
Hiroyuki Ishida
spellingShingle Aliakbar Dehno Khalaji
Hassan Hadadzadeh
Kazuma Gotoh
Hiroyuki Ishida
catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
Acta Crystallographica Section E
author_facet Aliakbar Dehno Khalaji
Hassan Hadadzadeh
Kazuma Gotoh
Hiroyuki Ishida
author_sort Aliakbar Dehno Khalaji
title catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
title_short catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
title_full catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
title_fullStr catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
title_full_unstemmed catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
title_sort catena-poly[[[n,n′-bis(3-methoxybenzylidene)ethylenediamine]copper(i)]-μ-thiocyanato-κ2n:s]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)]n, the CuI atom is coordinated in a distorted tetrahedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thiocyanate anions. The thiocyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808041925
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AT hassanhadadzadeh catenapolynn8242bis3methoxybenzylideneethylenediaminecopperi956thiocyanato9542ns
AT kazumagotoh catenapolynn8242bis3methoxybenzylideneethylenediaminecopperi956thiocyanato9542ns
AT hiroyukiishida catenapolynn8242bis3methoxybenzylideneethylenediaminecopperi956thiocyanato9542ns
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