2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene
The molecule of the title compound, C18H18Cl2N2O2, lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. Within the molecule, the planar units are parallel, but extend in opposite dir...
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International Union of Crystallography
2008-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808024355 |
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doaj-61307a7d895a45e19f7af86ae376fe772020-11-25T01:37:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649o1678o167810.1107/S16005368080243552,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzeneLi WangXue-Ni HeWen-Juan BaiWen-Kui DongZong-Li RenThe molecule of the title compound, C18H18Cl2N2O2, lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. In the crystal structure, the title compound exhibits a layer packing structure via weak π–π stacking interactions [intermolecular plane-to-plane distances between adjacent aromatic rings are 3.461 (3) Å]. Molecules in each layer are linked by intermolecular C—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536808024355 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Li Wang Xue-Ni He Wen-Juan Bai Wen-Kui Dong Zong-Li Ren |
spellingShingle |
Li Wang Xue-Ni He Wen-Juan Bai Wen-Kui Dong Zong-Li Ren 2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene Acta Crystallographica Section E |
author_facet |
Li Wang Xue-Ni He Wen-Juan Bai Wen-Kui Dong Zong-Li Ren |
author_sort |
Li Wang |
title |
2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene |
title_short |
2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene |
title_full |
2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene |
title_fullStr |
2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene |
title_full_unstemmed |
2,2′-Dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene |
title_sort |
2,2′-dichloro-1,1′-[(butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-09-01 |
description |
The molecule of the title compound, C18H18Cl2N2O2, lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. In the crystal structure, the title compound exhibits a layer packing structure via weak π–π stacking interactions [intermolecular plane-to-plane distances between adjacent aromatic rings are 3.461 (3) Å]. Molecules in each layer are linked by intermolecular C—H...O hydrogen-bonding interactions. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808024355 |
work_keys_str_mv |
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1725057141642887168 |