The crystal structure of Iridium Complex with Thiocarbamide

By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8...

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Main Authors:	T. M. Buslaeva, E. V. Kopylova, V. V. Kravchenko, G. A. Fedorova
Format:	Article
Language:	Russian
Published:	MIREA - Russian Technological University 2008-10-01
Series:	Тонкие химические технологии
Subjects:	иридий, тиомочевина, комплекс, синтез, структура
Online Access:	https://www.finechem-mirea.ru/jour/article/view/1532

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spelling	doaj-6111ace6652349aa9c9b24be729f04602021-07-28T13:23:51ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752008-10-013557611527The crystal structure of Iridium Complex with ThiocarbamideT. M. Buslaeva0E. V. Kopylova1V. V. Kravchenko2G. A. Fedorova3M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8.264(2) Å, c = 24.979(5) Å, β = 92.79(3), V = 2782.00(1) Å3 , Z = 8. The compound has a structure with two crystallographically independent iridium atoms: the coordination sphere of the Ir(1) atom involves two Cl atoms and four S atom, whereas the coordination sphere of the Ir(2) atom consists four Cl atoms and two S atom. Coordination of molecules Thio to the Iridium is realized though the sulfur atom.https://www.finechem-mirea.ru/jour/article/view/1532иридий, тиомочевина, комплекс, синтез, структура
collection	DOAJ
language	Russian
format	Article
sources	DOAJ
author	T. M. Buslaeva E. V. Kopylova V. V. Kravchenko G. A. Fedorova
spellingShingle	T. M. Buslaeva E. V. Kopylova V. V. Kravchenko G. A. Fedorova The crystal structure of Iridium Complex with Thiocarbamide Тонкие химические технологии иридий, тиомочевина, комплекс, синтез, структура
author_facet	T. M. Buslaeva E. V. Kopylova V. V. Kravchenko G. A. Fedorova
author_sort	T. M. Buslaeva
title	The crystal structure of Iridium Complex with Thiocarbamide
title_short	The crystal structure of Iridium Complex with Thiocarbamide
title_full	The crystal structure of Iridium Complex with Thiocarbamide
title_fullStr	The crystal structure of Iridium Complex with Thiocarbamide
title_full_unstemmed	The crystal structure of Iridium Complex with Thiocarbamide
title_sort	crystal structure of iridium complex with thiocarbamide
publisher	MIREA - Russian Technological University
series	Тонкие химические технологии
issn	2410-6593 2686-7575
publishDate	2008-10-01
description	By interaction of water solutions of K3[IrCl6] and Thiocarbamide (Thio, SC(NH2)2) at heating the complex of the composition [Ir(Thio)3Cl3] was synthesized. By the method of X-ray diffraction that the compound crystallizes in the monoclinic crystal system with space group C2/c, a = 13.492(3) Å, b = 8.264(2) Å, c = 24.979(5) Å, β = 92.79(3), V = 2782.00(1) Å3 , Z = 8. The compound has a structure with two crystallographically independent iridium atoms: the coordination sphere of the Ir(1) atom involves two Cl atoms and four S atom, whereas the coordination sphere of the Ir(2) atom consists four Cl atoms and two S atom. Coordination of molecules Thio to the Iridium is realized though the sulfur atom.
topic	иридий, тиомочевина, комплекс, синтез, структура
url	https://www.finechem-mirea.ru/jour/article/view/1532
work_keys_str_mv	AT tmbuslaeva thecrystalstructureofiridiumcomplexwiththiocarbamide AT evkopylova thecrystalstructureofiridiumcomplexwiththiocarbamide AT vvkravchenko thecrystalstructureofiridiumcomplexwiththiocarbamide AT gafedorova thecrystalstructureofiridiumcomplexwiththiocarbamide AT tmbuslaeva crystalstructureofiridiumcomplexwiththiocarbamide AT evkopylova crystalstructureofiridiumcomplexwiththiocarbamide AT vvkravchenko crystalstructureofiridiumcomplexwiththiocarbamide AT gafedorova crystalstructureofiridiumcomplexwiththiocarbamide
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The crystal structure of Iridium Complex with Thiocarbamide

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