Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)

Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)

The MoVI atom in the title co-crystal, [Mo(C14H12N2O4)O2(H2O)]·0.5C10H8N2, is O,N,O′-chelated by the deprotonated Schiff base and coordinated by the oxide and water O atoms in an octahedral geometry. The five-membered chelate ring is planar (r.m.s. deviation = 0.019&am...

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Main Authors: Ngui Khiong Ngan, Richard Chee Seng Wong, Kong Mun Lo, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811017260
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spelling doaj-60fefb14c1de476a8a30ce86b1704f1c2020-11-24T21:52:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m748m74810.1107/S1600536811017260Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)Ngui Khiong NganRichard Chee Seng WongKong Mun LoSeik Weng NgThe MoVI atom in the title co-crystal, [Mo(C14H12N2O4)O2(H2O)]·0.5C10H8N2, is O,N,O′-chelated by the deprotonated Schiff base and coordinated by the oxide and water O atoms in an octahedral geometry. The five-membered chelate ring is planar (r.m.s. deviation = 0.019 Å), but the six-membered chelate ring is puckered (r.m.s. deviation = 0.108 Å). Two mononuclear molecules are linked across a center of inversion by an O—Hwater...O hydrogen bond; adjacent dinuclear units are linked by an water–4,4′-bipyridine O—H...N hydrogen bond, generating a linear chain structure. The 4,4′-bipyridine molecule is disordered over two positions in a 1:1 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536811017260
collection DOAJ
language English
format Article
sources DOAJ
author Ngui Khiong Ngan
Richard Chee Seng Wong
Kong Mun Lo
Seik Weng Ng
spellingShingle Ngui Khiong Ngan
Richard Chee Seng Wong
Kong Mun Lo
Seik Weng Ng
Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
Acta Crystallographica Section E
author_facet Ngui Khiong Ngan
Richard Chee Seng Wong
Kong Mun Lo
Seik Weng Ng
author_sort Ngui Khiong Ngan
title Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
title_short Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
title_full Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
title_fullStr Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
title_full_unstemmed Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
title_sort aqua[n′-(3-ethoxy-2-oxidobenzyl-κo)furan-1-carbohydrazidato-κ2n′,o]dioxidomolybdenum(vi)–4,4′-bipyridine (2/1)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description The MoVI atom in the title co-crystal, [Mo(C14H12N2O4)O2(H2O)]·0.5C10H8N2, is O,N,O′-chelated by the deprotonated Schiff base and coordinated by the oxide and water O atoms in an octahedral geometry. The five-membered chelate ring is planar (r.m.s. deviation = 0.019 Å), but the six-membered chelate ring is puckered (r.m.s. deviation = 0.108 Å). Two mononuclear molecules are linked across a center of inversion by an O—Hwater...O hydrogen bond; adjacent dinuclear units are linked by an water–4,4′-bipyridine O—H...N hydrogen bond, generating a linear chain structure. The 4,4′-bipyridine molecule is disordered over two positions in a 1:1 ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811017260
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AT richardcheesengwong aquanamp82423ethoxy2oxidobenzylamp954ofuran1carbohydrazidatoamp9542namp8242odioxidomolybdenumviamp821144amp8242bipyridine21
AT kongmunlo aquanamp82423ethoxy2oxidobenzylamp954ofuran1carbohydrazidatoamp9542namp8242odioxidomolybdenumviamp821144amp8242bipyridine21
AT seikwengng aquanamp82423ethoxy2oxidobenzylamp954ofuran1carbohydrazidatoamp9542namp8242odioxidomolybdenumviamp821144amp8242bipyridine21
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