Crystal structures of tris[1-oxopyridine-2-olato(1−)]silicon(IV) chloride chloroform-d1 disolvate, tris[1-oxopyridine-2-olato(1−)]silicon(IV) chloride acetonitrile unquantified solvate, and fac-tris[1-oxopyridine-2-thiolato(1−)]silicon(IV) chloride chloroform-d1 disolvate

Crystal structures of tris[1-oxopyridine-2-olato(1−)]silicon(IV) chloride chloroform-d1 disolvate, tris[1-oxopyridine-2-olato(1−)]silicon(IV) chloride acetonitrile unquantified solvate, and fac-tris[1-oxopyridine-2-thiolato(1−)]silicon(IV) chloride chloroform-d1 disolvate

The cations in the title salts, [Si(OPO)3]Cl·2CDCl3, (I), [Si(OPO)3]Cl·xCH3CN, (II), and fac-[Si(OPTO)3]Cl·2CDCl3, (III) (OPO = 1-oxo-2-pyridinone, C5H4NO2, and OPTO = 1-oxo-2-pyridinethione, C5H4NOS), have distorted octahedral coordination spheres. The first two structures contain the same cation a...

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Bibliographic Details
Main Authors: Bradley M. Kraft, William W. Brennessel, Amy E. Ryan, Candace K. Benjamin
Format: Article
Language:English
Published: International Union of Crystallography 2015-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
silicon
pyridinone
pyridine N-oxide
pyrithione
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015022203

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http://scripts.iucr.org/cgi-bin/paper?S2056989015022203

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