Effect of improved sol-gel method on composition and micro morphology of Ca3Co4O9

Ca3Co4O9 is a potential high temperature thermoelectric material. We explore the hydrothermal treatment improved sol-gel method to prepare Ca3Co4O9 thermoelectric materials. We find that this treatment can increase the thermoelectric performance of the samples compared with the conventional citric a...

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Bibliographic Details
Main Authors: Hu Xuanye, Li Yanan, Wu Ping, Zhang Shiping, Huai Xiulan
Format: Article
Language:English
Published: EDP Sciences 2017-01-01
Series:EPJ Web of Conferences
Online Access:https://doi.org/10.1051/epjconf/201714013016
Description
Summary:Ca3Co4O9 is a potential high temperature thermoelectric material. We explore the hydrothermal treatment improved sol-gel method to prepare Ca3Co4O9 thermoelectric materials. We find that this treatment can increase the thermoelectric performance of the samples compared with the conventional citric acid sol-gel method. We also find the samples prepared by the improved sol-gel method have more uniform grain distribution, better densification, and less voids. At about 1000K, compared with the conventional sol-gel method, the power factor of the samples prepared by improved sol-gel method improves about 168%.
ISSN:2100-014X