Aquabis[1-hydroxy-2-(imidazol-3-ium-1-yl)-1,1′-ethylidenediphophonato-κ2O,O′]zinc(II) dihydrate

• Main Authors: Eleonora Freire, Daniel R. Vega
• Format: Article
• Language: English
• Published: International Union of Crystallography 2009-11-01
• Series: Acta Crystallographica Section E
• Online Access: http://scripts.iucr.org/cgi-bin/paper?S160053680904286X

In the title complex, [Zn(C5H9NO7P2)2(H2O)]·2H2O, the zinc atom is coordinated by two zoledronate anions [zoledronate = (2-(1-imidazole)-1-hydroxy-1,1′-ethylidenediphophonate)] and one water molecule. The coordination number is 5. There is one half-molecule in the asymmetric unit, the zinc atom being located on a twofold rotation axis passing through the metal centre and the coordinating water O atom. The anion exists as a zwitterion with an overall charge of −1; the protonated nitrogen in the ring has a positive charge and the two phosphonates groups each have a single negative charge. Intermolecular O—H...O hydrogen bonds link the molecules. An N—H...O interaction is also present.