4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate

4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate

The title benzene hemisolvate, C17H18N2O3·0.5C6H6, features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 Å) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about...

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Main Authors: Edward R. T. Tiekink, Anup Paul, Tushar S. Basu Baul
Format: Article
Language:English
Published: International Union of Crystallography 2010-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810003880
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spelling doaj-6082b122fd514969a1cadb8fc391f2e92020-11-24T21:22:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663o540o54010.1107/S16005368100038804-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvateEdward R. T. TiekinkAnup PaulTushar S. Basu BaulThe title benzene hemisolvate, C17H18N2O3·0.5C6H6, features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 Å) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about a centre of inversion. The dihedral angle formed between the benzene rings of the diazo molecule is 7.69 (12)°. In the crystal, centrosymmetrically related dimers associate via the eight-membered carboxylic acid dimer synthon, {...HOC(=O)}2, and these are connected into a supramolecular chain along the b axis via C—H...O contacts. http://scripts.iucr.org/cgi-bin/paper?S1600536810003880
collection DOAJ
language English
format Article
sources DOAJ
author Edward R. T. Tiekink
Anup Paul
Tushar S. Basu Baul
spellingShingle Edward R. T. Tiekink
Anup Paul
Tushar S. Basu Baul
4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
Acta Crystallographica Section E
author_facet Edward R. T. Tiekink
Anup Paul
Tushar S. Basu Baul
author_sort Edward R. T. Tiekink
title 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
title_short 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
title_full 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
title_fullStr 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
title_full_unstemmed 4-[(E)-(5-tert-Butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
title_sort 4-[(e)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoic acid benzene hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-03-01
description The title benzene hemisolvate, C17H18N2O3·0.5C6H6, features an essentially planar (the r.m.s. deviation of the non-H atoms, excluding methyl-C, is 0.071 Å) diazo molecule with an E conformation about the N=N bond, and a half-molecule of benzene disposed about a centre of inversion. The dihedral angle formed between the benzene rings of the diazo molecule is 7.69 (12)°. In the crystal, centrosymmetrically related dimers associate via the eight-membered carboxylic acid dimer synthon, {...HOC(=O)}2, and these are connected into a supramolecular chain along the b axis via C—H...O contacts.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810003880
work_keys_str_mv AT edwardrttiekink 4e5tertbutyl2hydroxyphenyldiazenylbenzoicacidbenzenehemisolvate
AT anuppaul 4e5tertbutyl2hydroxyphenyldiazenylbenzoicacidbenzenehemisolvate
AT tusharsbasubaul 4e5tertbutyl2hydroxyphenyldiazenylbenzoicacidbenzenehemisolvate
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