catena-Poly[[aquazinc(II)]-μ-N,N′-bis(2-cyano-3-ethoxy-3-oxoprop-1-enyl)benzene-1,2-diaminido]

• Main Authors: Monica Fuchs, Thomas Zevaco, Eckhard Dinjus, Olaf Walter
• Format: Article
• Language: English
• Published: International Union of Crystallography 2014-05-01
• Series: Acta Crystallographica Section E
• Online Access: http://scripts.iucr.org/cgi-bin/paper?S1600536814008381

The slightly yellow-coloured title complex, [Zn(C18H16N4O4)(H2O)]n, crystallizes with one molecule in the asymmetric unit. The structure clearly shows the mer-η4O,O,N,N-binding mode of the N,N′-bis-(2-cyano-ethylpropenoyl)-1,2-diamidobenzene ligand stabilizing the Zn centre of a distorted octahedral environment. The fifth coordination site in one apical position is held by a coordinating solvent water molecule whereas the complete octahedral coordination sphere is completed by coordination of one N atom from a CN group of a neighbouring molecule, leading to the final polymeric structure consisting of zigzag staggered chains in parallel orientation along the c-axis direction. Between the coordinated water solvent molecule and the N atoms of uncoordinated cyano-groups of neighboured units, two H-bridge bonds are formed. One of these H-bridge bonds is of inter- whereas the other of intra-strand nature, leading to a two-dimensional network parallel to (110) stabilizing the supramolecular structure. Six Zn—O or Zn—N bonds are found with lengths ranging from 2.061 (1) to 2.185 (1) Å and bond angles about the Zn atom are clustered in the ranges 79.83 (4)–104.21 (4) and 167.05 (4)–170.28 (4)°.