(4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)

(4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)

In the title compound, [Pd(CF3)(C6H4F)(C6H16N2)], the PdII cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and by one C atom each from a 4-fluorophenyl and a trifluoromethyl ligand, in a distorted rectangular-planar geometry, with an average deviation...

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Main Authors: Youzhi Du, ChangGe Zheng
Format: Article
Language:English
Published: International Union of Crystallography 2014-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814007855
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spelling doaj-6023c75f2315400ab80714f40ba5b3a92020-11-24T21:29:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-05-01705m179m17910.1107/S1600536814007855vn2082(4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)Youzhi Du0ChangGe Zheng1School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People's Republic of ChinaSchool of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People's Republic of ChinaIn the title compound, [Pd(CF3)(C6H4F)(C6H16N2)], the PdII cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and by one C atom each from a 4-fluorophenyl and a trifluoromethyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the PdII atom range from 83.14 (10) to 97.25 (12)°.http://scripts.iucr.org/cgi-bin/paper?S1600536814007855
collection DOAJ
language English
format Article
sources DOAJ
author Youzhi Du
ChangGe Zheng
spellingShingle Youzhi Du
ChangGe Zheng
(4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)
Acta Crystallographica Section E
author_facet Youzhi Du
ChangGe Zheng
author_sort Youzhi Du
title (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)
title_short (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)
title_full (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)
title_fullStr (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)
title_full_unstemmed (4-Fluorophenyl-κC)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)(trifluoromethyl-κC)palladium(II)
title_sort (4-fluorophenyl-κc)(n,n,n′,n′-tetramethylethylenediamine-κ2n,n′)(trifluoromethyl-κc)palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-05-01
description In the title compound, [Pd(CF3)(C6H4F)(C6H16N2)], the PdII cation is four-coordinated by the two N atoms of the N,N,N′,N′-tetramethylethylenediamine ligand and by one C atom each from a 4-fluorophenyl and a trifluoromethyl ligand, in a distorted rectangular-planar geometry, with an average deviation from the least-squares plane of 0.066 (2) Å. The central coordination angles with the PdII atom range from 83.14 (10) to 97.25 (12)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814007855
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AT changgezheng 4fluorophenylkcnnnntetramethylethylenediaminek2nntrifluoromethylkcpalladiumii
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