Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
Phosphorus-doped activated carbon (P@AC), prepared by wet impregnation method, can serve as efficient metal-free catalyst for the dehydroaromatization of n-hexane to benzene under mild conditions. The effect of phosphorus amount and phosphorus sources including phenylphosphonic acid (PPOA), phosphor...
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2021-08-01
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doaj-6014eb92ee0b45a48fef7118c1bbad542021-05-08T04:22:16ZengElsevierCatalysis Communications1873-39052021-08-01156106318Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reactionYong Li0Hong Zhao1Siyuan Chen2Shuhao Bao3Feifei Xing4Biao Jiang5Green Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; College of Sciences, Shanghai University, Shanghai 200444, ChinaGreen Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; Corresponding authors.Green Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, ChinaGreen Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; College of Sciences, Shanghai University, Shanghai 200444, ChinaCollege of Sciences, Shanghai University, Shanghai 200444, ChinaGreen Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; Corresponding authors.Phosphorus-doped activated carbon (P@AC), prepared by wet impregnation method, can serve as efficient metal-free catalyst for the dehydroaromatization of n-hexane to benzene under mild conditions. The effect of phosphorus amount and phosphorus sources including phenylphosphonic acid (PPOA), phosphorus acid (H3PO4), triphenylphosphine (TPP), and tributylphosphine (TBP) on catalytic performance of P@AC were investigated. Combining with characterization analysis, functional groups containing -P(O)(OH) on the carbon surface are believed to be the active sites for dehydroaromatization catalysis.http://www.sciencedirect.com/science/article/pii/S1566736721000418Activated carbonP-dopingDehydroaromatizationPhosphorus sourcen-Hexane |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Yong Li Hong Zhao Siyuan Chen Shuhao Bao Feifei Xing Biao Jiang |
spellingShingle |
Yong Li Hong Zhao Siyuan Chen Shuhao Bao Feifei Xing Biao Jiang Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction Catalysis Communications Activated carbon P-doping Dehydroaromatization Phosphorus source n-Hexane |
author_facet |
Yong Li Hong Zhao Siyuan Chen Shuhao Bao Feifei Xing Biao Jiang |
author_sort |
Yong Li |
title |
Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction |
title_short |
Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction |
title_full |
Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction |
title_fullStr |
Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction |
title_full_unstemmed |
Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction |
title_sort |
phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction |
publisher |
Elsevier |
series |
Catalysis Communications |
issn |
1873-3905 |
publishDate |
2021-08-01 |
description |
Phosphorus-doped activated carbon (P@AC), prepared by wet impregnation method, can serve as efficient metal-free catalyst for the dehydroaromatization of n-hexane to benzene under mild conditions. The effect of phosphorus amount and phosphorus sources including phenylphosphonic acid (PPOA), phosphorus acid (H3PO4), triphenylphosphine (TPP), and tributylphosphine (TBP) on catalytic performance of P@AC were investigated. Combining with characterization analysis, functional groups containing -P(O)(OH) on the carbon surface are believed to be the active sites for dehydroaromatization catalysis. |
topic |
Activated carbon P-doping Dehydroaromatization Phosphorus source n-Hexane |
url |
http://www.sciencedirect.com/science/article/pii/S1566736721000418 |
work_keys_str_mv |
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_version_ |
1721455150816559104 |