Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction

Phosphorus-doped activated carbon (P@AC), prepared by wet impregnation method, can serve as efficient metal-free catalyst for the dehydroaromatization of n-hexane to benzene under mild conditions. The effect of phosphorus amount and phosphorus sources including phenylphosphonic acid (PPOA), phosphor...

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Main Authors: Yong Li, Hong Zhao, Siyuan Chen, Shuhao Bao, Feifei Xing, Biao Jiang
Format: Article
Language:English
Published: Elsevier 2021-08-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736721000418
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spelling doaj-6014eb92ee0b45a48fef7118c1bbad542021-05-08T04:22:16ZengElsevierCatalysis Communications1873-39052021-08-01156106318Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reactionYong Li0Hong Zhao1Siyuan Chen2Shuhao Bao3Feifei Xing4Biao Jiang5Green Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; College of Sciences, Shanghai University, Shanghai 200444, ChinaGreen Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; Corresponding authors.Green Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, ChinaGreen Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; College of Sciences, Shanghai University, Shanghai 200444, ChinaCollege of Sciences, Shanghai University, Shanghai 200444, ChinaGreen Chemical Engineering Technology Research Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; Corresponding authors.Phosphorus-doped activated carbon (P@AC), prepared by wet impregnation method, can serve as efficient metal-free catalyst for the dehydroaromatization of n-hexane to benzene under mild conditions. The effect of phosphorus amount and phosphorus sources including phenylphosphonic acid (PPOA), phosphorus acid (H3PO4), triphenylphosphine (TPP), and tributylphosphine (TBP) on catalytic performance of P@AC were investigated. Combining with characterization analysis, functional groups containing -P(O)(OH) on the carbon surface are believed to be the active sites for dehydroaromatization catalysis.http://www.sciencedirect.com/science/article/pii/S1566736721000418Activated carbonP-dopingDehydroaromatizationPhosphorus sourcen-Hexane
collection DOAJ
language English
format Article
sources DOAJ
author Yong Li
Hong Zhao
Siyuan Chen
Shuhao Bao
Feifei Xing
Biao Jiang
spellingShingle Yong Li
Hong Zhao
Siyuan Chen
Shuhao Bao
Feifei Xing
Biao Jiang
Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
Catalysis Communications
Activated carbon
P-doping
Dehydroaromatization
Phosphorus source
n-Hexane
author_facet Yong Li
Hong Zhao
Siyuan Chen
Shuhao Bao
Feifei Xing
Biao Jiang
author_sort Yong Li
title Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
title_short Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
title_full Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
title_fullStr Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
title_full_unstemmed Phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
title_sort phosphorus-doped activated carbon catalyst for n-hexane dehydroaromatization reaction
publisher Elsevier
series Catalysis Communications
issn 1873-3905
publishDate 2021-08-01
description Phosphorus-doped activated carbon (P@AC), prepared by wet impregnation method, can serve as efficient metal-free catalyst for the dehydroaromatization of n-hexane to benzene under mild conditions. The effect of phosphorus amount and phosphorus sources including phenylphosphonic acid (PPOA), phosphorus acid (H3PO4), triphenylphosphine (TPP), and tributylphosphine (TBP) on catalytic performance of P@AC were investigated. Combining with characterization analysis, functional groups containing -P(O)(OH) on the carbon surface are believed to be the active sites for dehydroaromatization catalysis.
topic Activated carbon
P-doping
Dehydroaromatization
Phosphorus source
n-Hexane
url http://www.sciencedirect.com/science/article/pii/S1566736721000418
work_keys_str_mv AT yongli phosphorusdopedactivatedcarboncatalystfornhexanedehydroaromatizationreaction
AT hongzhao phosphorusdopedactivatedcarboncatalystfornhexanedehydroaromatizationreaction
AT siyuanchen phosphorusdopedactivatedcarboncatalystfornhexanedehydroaromatizationreaction
AT shuhaobao phosphorusdopedactivatedcarboncatalystfornhexanedehydroaromatizationreaction
AT feifeixing phosphorusdopedactivatedcarboncatalystfornhexanedehydroaromatizationreaction
AT biaojiang phosphorusdopedactivatedcarboncatalystfornhexanedehydroaromatizationreaction
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