Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]

Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]

The title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)2·3H2O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand. The asymmetric unit contains one half-molecule, th...

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Main Authors: Jun Zhang, Xiao-Dan Chen, Huai-Hong Zhang, Bai-Wang Sun
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809030475
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spelling doaj-5f2985ec816c41b495c5c8b88fbbc1532020-11-25T02:46:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1136m113610.1107/S1600536809030475Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]Jun ZhangXiao-Dan ChenHuai-Hong ZhangBai-Wang SunThe title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)2·3H2O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each CuII atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H...N hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809030475
collection DOAJ
language English
format Article
sources DOAJ
author Jun Zhang
Xiao-Dan Chen
Huai-Hong Zhang
Bai-Wang Sun
spellingShingle Jun Zhang
Xiao-Dan Chen
Huai-Hong Zhang
Bai-Wang Sun
Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
Acta Crystallographica Section E
author_facet Jun Zhang
Xiao-Dan Chen
Huai-Hong Zhang
Bai-Wang Sun
author_sort Jun Zhang
title Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
title_short Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
title_full Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
title_fullStr Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
title_full_unstemmed Bis{μ-2-[1-(2-Pyridylmethylimino)ethyl]phenolato}bis[azidocopper(II)]
title_sort bis{μ-2-[1-(2-pyridylmethylimino)ethyl]phenolato}bis[azidocopper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description The title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)2·3H2O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each CuII atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809030475
work_keys_str_mv AT junzhang bisamp956212pyridylmethyliminoethylphenolatobisazidocopperii
AT xiaodanchen bisamp956212pyridylmethyliminoethylphenolatobisazidocopperii
AT huaihongzhang bisamp956212pyridylmethyliminoethylphenolatobisazidocopperii
AT baiwangsun bisamp956212pyridylmethyliminoethylphenolatobisazidocopperii
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