Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]

Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]

In the title coordination polymer, {[BaCu2(C9H4NO5)2(C3H4N2)2(H2O)4]·2H2O}n, the Ba2+ cation is decacoordinate, ligated by four aqua ligands and four [Cu(C9H4O5N)(C3H4N2)] `complex ligands'. The CuII-containing complex-ligands are bridged by the Ba2+ cations, resulting in a one-dimensi...

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Main Authors: Peng Zhang, Kaihui Li, Chongzhen Mei
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808000597
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spelling doaj-5e98cdd65e8b48fb81220312eee2420d2020-11-25T03:05:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m356m35610.1107/S1600536808000597Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]Peng ZhangKaihui LiChongzhen MeiIn the title coordination polymer, {[BaCu2(C9H4NO5)2(C3H4N2)2(H2O)4]·2H2O}n, the Ba2+ cation is decacoordinate, ligated by four aqua ligands and four [Cu(C9H4O5N)(C3H4N2)] `complex ligands'. The CuII-containing complex-ligands are bridged by the Ba2+ cations, resulting in a one-dimensional polymeric chain structure. The crystal structure is maintained via N—H...O and O—H...O hydrogen bonds. There is one disordered solvent water molecule in the asymmetric unit, with occupancies of 0.44 (2) and 0.56 (2).http://scripts.iucr.org/cgi-bin/paper?S1600536808000597
collection DOAJ
language English
format Article
sources DOAJ
author Peng Zhang
Kaihui Li
Chongzhen Mei
spellingShingle Peng Zhang
Kaihui Li
Chongzhen Mei
Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
Acta Crystallographica Section E
author_facet Peng Zhang
Kaihui Li
Chongzhen Mei
author_sort Peng Zhang
title Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_short Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_full Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_fullStr Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_full_unstemmed Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_sort poly[[tetraaquabis(1h-imidazole-κn3)bis[2-(oxaloamino)benzoato(3–)]dicopper(ii)barium(ii)] dihydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description In the title coordination polymer, {[BaCu2(C9H4NO5)2(C3H4N2)2(H2O)4]·2H2O}n, the Ba2+ cation is decacoordinate, ligated by four aqua ligands and four [Cu(C9H4O5N)(C3H4N2)] `complex ligands'. The CuII-containing complex-ligands are bridged by the Ba2+ cations, resulting in a one-dimensional polymeric chain structure. The crystal structure is maintained via N—H...O and O—H...O hydrogen bonds. There is one disordered solvent water molecule in the asymmetric unit, with occupancies of 0.44 (2) and 0.56 (2).
url http://scripts.iucr.org/cgi-bin/paper?S1600536808000597
work_keys_str_mv AT pengzhang polytetraaquabis1himidazole954n3bis2oxaloaminobenzoato38211dicopperiibariumiidihydrate
AT kaihuili polytetraaquabis1himidazole954n3bis2oxaloaminobenzoato38211dicopperiibariumiidihydrate
AT chongzhenmei polytetraaquabis1himidazole954n3bis2oxaloaminobenzoato38211dicopperiibariumiidihydrate
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