Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)

Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)

In the crystal structure of the title compound, [Mn(C5H7O2)2(C12H8N2)], the Mn2+ cation is coordinated by one bidentate 1,10-phenanthroline ligand and two acetylacetonate anions within a slightly distorted N2O4 octahedron. The asymmetric unit consists of one Mn2+ cation situated on a twofold rotatio...

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Main Authors: Stefan Suckert, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2013-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813028614
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spelling doaj-5e8c1362b0ed49cba1a40b6ef3be154f2020-11-25T01:56:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m620m62010.1107/S1600536813028614Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)Stefan SuckertInke JessChristian NätherIn the crystal structure of the title compound, [Mn(C5H7O2)2(C12H8N2)], the Mn2+ cation is coordinated by one bidentate 1,10-phenanthroline ligand and two acetylacetonate anions within a slightly distorted N2O4 octahedron. The asymmetric unit consists of one Mn2+ cation situated on a twofold rotation axis, one half of a 1,10-phenanthroline ligand and one acetylacetonate anion. In comparison with the previous determination based on visually estimated intensities recorded on precession photographs, the current redetermination with image-plate data reveals bond lengths and angles with much higher precision.http://scripts.iucr.org/cgi-bin/paper?S1600536813028614
collection DOAJ
language English
format Article
sources DOAJ
author Stefan Suckert
Inke Jess
Christian Näther
spellingShingle Stefan Suckert
Inke Jess
Christian Näther
Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)
Acta Crystallographica Section E
author_facet Stefan Suckert
Inke Jess
Christian Näther
author_sort Stefan Suckert
title Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)
title_short Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)
title_full Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)
title_fullStr Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)
title_full_unstemmed Redetermination of bis(acetylacetonato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)manganese(II)
title_sort redetermination of bis(acetylacetonato-κ2o,o′)(1,10-phenanthroline-κ2n,n′)manganese(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-11-01
description In the crystal structure of the title compound, [Mn(C5H7O2)2(C12H8N2)], the Mn2+ cation is coordinated by one bidentate 1,10-phenanthroline ligand and two acetylacetonate anions within a slightly distorted N2O4 octahedron. The asymmetric unit consists of one Mn2+ cation situated on a twofold rotation axis, one half of a 1,10-phenanthroline ligand and one acetylacetonate anion. In comparison with the previous determination based on visually estimated intensities recorded on precession photographs, the current redetermination with image-plate data reveals bond lengths and angles with much higher precision.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813028614
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AT inkejess redeterminationofbisacetylacetonato9542oo8242110phenanthroline9542nn8242manganeseii
AT christiann228ther redeterminationofbisacetylacetonato9542oo8242110phenanthroline9542nn8242manganeseii
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