trans-Bis(thiocyanato-κN)tetrakis(3,4,5-trimethyl-1H-pyrazole-κN2)nickel(II)–3,4,5-trimethyl-1H-pyrazole (1/1)

trans-Bis(thiocyanato-κN)tetrakis(3,4,5-trimethyl-1H-pyrazole-κN2)nickel(II)–3,4,5-trimethyl-1H-pyrazole (1/1)

In the title compound, [Ni(NCS)2(C6H10N2)4]·C6H10N2, the asymmetric unit comprises a NiII complex and a co-crystallised molecule of 3,4,5-trimethyl-1H-pyrazole (PzMe3). The NiII atom is coordinated by four PzMe3 molecules and two thiocyanate anions to define a trans N4S2 distorted octah...

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Bibliographic Details
Main Authors: Moayad Hossaini Sadr, James T. Engle, Christopher J. Ziegler, Behzad Soltani, Zahra Mousavi
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811041419
Description
Summary:In the title compound, [Ni(NCS)2(C6H10N2)4]·C6H10N2, the asymmetric unit comprises a NiII complex and a co-crystallised molecule of 3,4,5-trimethyl-1H-pyrazole (PzMe3). The NiII atom is coordinated by four PzMe3 molecules and two thiocyanate anions to define a trans N4S2 distorted octahedral geometry. A number of intramolecular N—H...N, N—H...S and C—H...N interactions contribute to the stability of the complex. The crystal structure is stabilized by intermolecular N—H...S interactions, which link neighbouring molecules into chains along the a axis.
ISSN:1600-5368

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