Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air

<p class="Default">High concentration of phosphates in the water can lead to eutrophication which leads to uncontrolled growth of algae (algae blooming). It underlies the need for determining the concentration of phosphate in the aquatic environment. However, the concentration of pho...

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Main Authors: Asep Saefumullah, Ratsania Rahmaniati H
Format: Article
Language:Indonesian
Published: Syarif Hidayatullah Jakarta State Islamic University 2016-08-01
Series:Jurnal Kimia Valensi
Subjects:
DGT
Online Access:http://journal.uinjkt.ac.id/index.php/valensi/article/view/3597
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spelling doaj-5e17c9377498480586621bbe01baa3bb2020-11-24T22:34:27ZindSyarif Hidayatullah Jakarta State Islamic UniversityJurnal Kimia Valensi2460-60652548-30132016-08-0100202510.15408/jkv.v0i0.35972733Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam AirAsep Saefumullah0Ratsania Rahmaniati H1Departemen Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas IndonesiaDepartemen Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Indonesia<p class="Default">High concentration of phosphates in the water can lead to eutrophication which leads to uncontrolled growth of algae (algae blooming). It underlies the need for determining the concentration of phosphate in the aquatic environment. However, the concentration of phosphate may change during storage of samples so that an accurate analysis difficult to achieve unless carried out in-situ. DGT (Diffusive Gradient in Thin Films) is an in-situ measurement method developed for measuring phosphate and metal. In this study the use of Fe-Al-Oxide as a binding gel that is expected to bind phosphate with a capacity greater than ferrihydrite. N, N'-methylenebisacrylamide is used as a substitute for commercial DGT Crosslinker as crosslinking for a cheaper price and selective for small molecule. Ferrihydrite-DGT and Fe-Al-Oxide-DGT are tested with a variety of concentrations, pH, and contact time. In both methods DGT found that the pH for phosphate measurements performed at pH 3. Capacity of Fe-Al-Oxide binding gel known to be higher than the ferrihydrite binding gel with result C<sub>ferrihydrite-DGT</sub>:C<sub>start</sub> is 76% and C<sub>Fe-Al-Oxide-DGT</sub>:C<sub>start</sub> is 82%.</p><p class="Default"><strong><em>DOI :</em></strong><a href="http://dx.doi.org/10.15408/jkv.v0i0.3597"><em>http://dx.doi.org/10.15408/jkv.v0i0.3597</em></a></p><p><strong> </strong></p> <p><strong> </strong></p>http://journal.uinjkt.ac.id/index.php/valensi/article/view/3597DGTferrihydriteFe-Al-OxidephosphateN,N-methylenebisacrylamide
collection DOAJ
language Indonesian
format Article
sources DOAJ
author Asep Saefumullah
Ratsania Rahmaniati H
spellingShingle Asep Saefumullah
Ratsania Rahmaniati H
Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air
Jurnal Kimia Valensi
DGT
ferrihydrite
Fe-Al-Oxide
phosphate
N,N-methylenebisacrylamide
author_facet Asep Saefumullah
Ratsania Rahmaniati H
author_sort Asep Saefumullah
title Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air
title_short Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air
title_full Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air
title_fullStr Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air
title_full_unstemmed Pengembangan Metode DGT (Diffusive Gradient In Thin Film) dengan Binding Gel Fe-Al-Oksida dan Pengikat Silang N,N’-Methylenebisacrylamide untuk Penyerapan Fosfat dalam Air
title_sort pengembangan metode dgt (diffusive gradient in thin film) dengan binding gel fe-al-oksida dan pengikat silang n,n’-methylenebisacrylamide untuk penyerapan fosfat dalam air
publisher Syarif Hidayatullah Jakarta State Islamic University
series Jurnal Kimia Valensi
issn 2460-6065
2548-3013
publishDate 2016-08-01
description <p class="Default">High concentration of phosphates in the water can lead to eutrophication which leads to uncontrolled growth of algae (algae blooming). It underlies the need for determining the concentration of phosphate in the aquatic environment. However, the concentration of phosphate may change during storage of samples so that an accurate analysis difficult to achieve unless carried out in-situ. DGT (Diffusive Gradient in Thin Films) is an in-situ measurement method developed for measuring phosphate and metal. In this study the use of Fe-Al-Oxide as a binding gel that is expected to bind phosphate with a capacity greater than ferrihydrite. N, N'-methylenebisacrylamide is used as a substitute for commercial DGT Crosslinker as crosslinking for a cheaper price and selective for small molecule. Ferrihydrite-DGT and Fe-Al-Oxide-DGT are tested with a variety of concentrations, pH, and contact time. In both methods DGT found that the pH for phosphate measurements performed at pH 3. Capacity of Fe-Al-Oxide binding gel known to be higher than the ferrihydrite binding gel with result C<sub>ferrihydrite-DGT</sub>:C<sub>start</sub> is 76% and C<sub>Fe-Al-Oxide-DGT</sub>:C<sub>start</sub> is 82%.</p><p class="Default"><strong><em>DOI :</em></strong><a href="http://dx.doi.org/10.15408/jkv.v0i0.3597"><em>http://dx.doi.org/10.15408/jkv.v0i0.3597</em></a></p><p><strong> </strong></p> <p><strong> </strong></p>
topic DGT
ferrihydrite
Fe-Al-Oxide
phosphate
N,N-methylenebisacrylamide
url http://journal.uinjkt.ac.id/index.php/valensi/article/view/3597
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AT ratsaniarahmaniatih pengembanganmetodedgtdiffusivegradientinthinfilmdenganbindinggelfealoksidadanpengikatsilangnnmethylenebisacrylamideuntukpenyerapanfosfatdalamair
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