μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)

μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)

The crystal structure of the title complex, [Cu2Br3(OH)(C11H13Br0.5Cl1.5N2O)2], consists of two (2-halo-6-oxazolinyl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The CuII atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetragonal–pyramidal core, an...

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Main Authors: Andy Ch. Laungani, Manfred Keller, Bernhard Breit
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807058862
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spelling doaj-5da8b2d96658493fb856edd6dde98bc12020-11-24T21:05:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m24m2510.1107/S1600536807058862μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)Andy Ch. LaunganiManfred KellerBernhard BreitThe crystal structure of the title complex, [Cu2Br3(OH)(C11H13Br0.5Cl1.5N2O)2], consists of two (2-halo-6-oxazolinyl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The CuII atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetragonal–pyramidal core, and relatively short contacts to the bridging atoms (Cu—μ-OH and Cu—μ-Br). There are two symmetry-independent half-molecules in the asymmetric unit, which differ only in the arrangement of the isopropyl group. The molecules are located on a twofold rotation axes.http://scripts.iucr.org/cgi-bin/paper?S1600536807058862
collection DOAJ
language English
format Article
sources DOAJ
author Andy Ch. Laungani
Manfred Keller
Bernhard Breit
spellingShingle Andy Ch. Laungani
Manfred Keller
Bernhard Breit
μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
Acta Crystallographica Section E
author_facet Andy Ch. Laungani
Manfred Keller
Bernhard Breit
author_sort Andy Ch. Laungani
title μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_short μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_full μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_fullStr μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_full_unstemmed μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_sort μ-bromido-dibromido-μ-hydroxido-bis[(4s)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(ii) (halo: cl/br = 3:1)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The crystal structure of the title complex, [Cu2Br3(OH)(C11H13Br0.5Cl1.5N2O)2], consists of two (2-halo-6-oxazolinyl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The CuII atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetragonal–pyramidal core, and relatively short contacts to the bridging atoms (Cu—μ-OH and Cu—μ-Br). There are two symmetry-independent half-molecules in the asymmetric unit, which differ only in the arrangement of the isopropyl group. The molecules are located on a twofold rotation axes.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807058862
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AT manfredkeller 956bromidodibromido956hydroxidobis4s2halo64isopropyl45dihydrooxazol2ylpyridinedicopperiihaloclbr31
AT bernhardbreit 956bromidodibromido956hydroxidobis4s2halo64isopropyl45dihydrooxazol2ylpyridinedicopperiihaloclbr31
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