μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
The crystal structure of the title complex, [Cu2Br3(OH)(C11H13Br0.5Cl1.5N2O)2], consists of two (2-halo-6-oxazolinyl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The CuII atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetragonal–pyramidal core, an...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807058862 |
| Summary: | The crystal structure of the title complex, [Cu2Br3(OH)(C11H13Br0.5Cl1.5N2O)2], consists of two (2-halo-6-oxazolinyl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The CuII atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetragonal–pyramidal core, and relatively short contacts to the bridging atoms (Cu—μ-OH and Cu—μ-Br). There are two symmetry-independent half-molecules in the asymmetric unit, which differ only in the arrangement of the isopropyl group. The molecules are located on a twofold rotation axes. |
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| ISSN: | 1600-5368 |