catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]

catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]

In the title complex, [Fe(C2O4)(C5H4N2O4)]n, the FeII ion is coordinated by two oxalate anions and a pyrimidine-2-carboxylic acid ligand in a slightly distorted octahedral geometry. Each oxalate anion chelates to two FeII ions, forming chains along the a axis. The chains are further connected by O&a...

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Main Authors: Jiong-Peng Zhao, Fu-Chen Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810030023
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spelling doaj-5cf429cf60064b04bebc9ca174c3c6f22020-11-25T01:05:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1059m105910.1107/S1600536810030023catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]Jiong-Peng ZhaoFu-Chen LiuIn the title complex, [Fe(C2O4)(C5H4N2O4)]n, the FeII ion is coordinated by two oxalate anions and a pyrimidine-2-carboxylic acid ligand in a slightly distorted octahedral geometry. Each oxalate anion chelates to two FeII ions, forming chains along the a axis. The chains are further connected by O—H...O and C—H...O hydrogen bonds, stabilizing the structure. An intramolecular O—H...N interaction results in a five-membered ring. http://scripts.iucr.org/cgi-bin/paper?S1600536810030023
collection DOAJ
language English
format Article
sources DOAJ
author Jiong-Peng Zhao
Fu-Chen Liu
spellingShingle Jiong-Peng Zhao
Fu-Chen Liu
catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]
Acta Crystallographica Section E
author_facet Jiong-Peng Zhao
Fu-Chen Liu
author_sort Jiong-Peng Zhao
title catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]
title_short catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]
title_full catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]
title_fullStr catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]
title_full_unstemmed catena-Poly[[(pyrimidine-2-carboxylic acid)iron(II)]-μ-oxalato]
title_sort catena-poly[[(pyrimidine-2-carboxylic acid)iron(ii)]-μ-oxalato]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description In the title complex, [Fe(C2O4)(C5H4N2O4)]n, the FeII ion is coordinated by two oxalate anions and a pyrimidine-2-carboxylic acid ligand in a slightly distorted octahedral geometry. Each oxalate anion chelates to two FeII ions, forming chains along the a axis. The chains are further connected by O—H...O and C—H...O hydrogen bonds, stabilizing the structure. An intramolecular O—H...N interaction results in a five-membered ring.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810030023
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AT fuchenliu catenapolypyrimidine2carboxylicacidironiiamp956oxalato
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