2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole

2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole

In the title compound, C26H18Cl2N2O5S, the carbazole ring system is essentially planar with a maximum deviation of 0.0498 (16) Å for the N atom. The carbazole ring system is almost orthogonal to the phenylsulfonyl and dichloro-substituted nitrophenyl rings, making dihedral angles of 84.23 (7) and 85...

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Main Authors: P. Narayanan, K. Sethusankar, Velu Saravanan, Arasambattu K. Mohanakrishnan
Format: Article
Language:English
Published: International Union of Crystallography 2014-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814001342
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spelling doaj-5cbd831a06df41018e7067b91f409bab2020-11-25T02:19:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702o212o21310.1107/S1600536814001342rk24202-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazoleP. Narayanan0K. Sethusankar1Velu Saravanan2Arasambattu K. Mohanakrishnan3Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Organic Chemistry, University of Madras, Maraimalai campus, Chennai 600 025, IndiaDepartment of Organic Chemistry, University of Madras, Maraimalai campus, Chennai 600 025, IndiaIn the title compound, C26H18Cl2N2O5S, the carbazole ring system is essentially planar with a maximum deviation of 0.0498 (16) Å for the N atom. The carbazole ring system is almost orthogonal to the phenylsulfonyl and dichloro-substituted nitrophenyl rings, making dihedral angles of 84.23 (7) and 85.46 (12)°, respectively. The molecular structure features intramolecular C—H...O interactions, which generate two S(6) ring motifs. In the crystal, molecules are linked by C—Cl...O halogen bonds [3.016 (3) Å, 166.63 (5)°], which generate infinite C(8) chains running parallel to [010].http://scripts.iucr.org/cgi-bin/paper?S1600536814001342
collection DOAJ
language English
format Article
sources DOAJ
author P. Narayanan
K. Sethusankar
Velu Saravanan
Arasambattu K. Mohanakrishnan
spellingShingle P. Narayanan
K. Sethusankar
Velu Saravanan
Arasambattu K. Mohanakrishnan
2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole
Acta Crystallographica Section E
author_facet P. Narayanan
K. Sethusankar
Velu Saravanan
Arasambattu K. Mohanakrishnan
author_sort P. Narayanan
title 2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole
title_short 2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole
title_full 2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole
title_fullStr 2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole
title_full_unstemmed 2-(4,5-Dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole
title_sort 2-(4,5-dichloro-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9h-carbazole
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-02-01
description In the title compound, C26H18Cl2N2O5S, the carbazole ring system is essentially planar with a maximum deviation of 0.0498 (16) Å for the N atom. The carbazole ring system is almost orthogonal to the phenylsulfonyl and dichloro-substituted nitrophenyl rings, making dihedral angles of 84.23 (7) and 85.46 (12)°, respectively. The molecular structure features intramolecular C—H...O interactions, which generate two S(6) ring motifs. In the crystal, molecules are linked by C—Cl...O halogen bonds [3.016 (3) Å, 166.63 (5)°], which generate infinite C(8) chains running parallel to [010].
url http://scripts.iucr.org/cgi-bin/paper?S1600536814001342
work_keys_str_mv AT pnarayanan 245dichloro2nitrophenyl4methoxy3methyl9phenylsulfonyl9hcarbazole
AT ksethusankar 245dichloro2nitrophenyl4methoxy3methyl9phenylsulfonyl9hcarbazole
AT velusaravanan 245dichloro2nitrophenyl4methoxy3methyl9phenylsulfonyl9hcarbazole
AT arasambattukmohanakrishnan 245dichloro2nitrophenyl4methoxy3methyl9phenylsulfonyl9hcarbazole
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